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CAS RN: 29892-37-3 | Product Number: C2719
Chloro(dimethylsulfide)gold(I)
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Purity: >97.0%(T)
Synonyms:
- (Dimethylsulfide)gold(I) Chloride
Product Documents:
| Size | Unit Price | Saitama (Kawaguchi) | Hyogo (Amagasaki) | Stock in other WH |
Shipping Information
|
|---|---|---|---|---|---|
| 200MG |
¥10,200
|
5 | 2 | It can be shipped in about 2 weeks after ordering | |
| 1G |
¥30,600
|
It can be shipped in about 2-3 business days after ordering | 11 | ≥100 |
* Available Stock: Prompt shipment (for products) in Saitama/Hyogo warehouse. Stock In Other WH: Shipment in about 2-3 Business Days from Saitama warehouse. Please contact us
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*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
* The displayed price is the unit price and does not include consumption tax. The unit prices displayed are the latest and are subject to change without notice.
* To send your quote request for bulk quantities, please click on the "Request Bulk Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | C2719 |
| Purity / Analysis Method | >97.0%(T) |
| Molecular Formula / Molecular Weight | C__2H__6AuClS = 294.55 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Light Sensitive,Air Sensitive,Heat Sensitive |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image), 200MG-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 29892-37-3 |
| Reaxys Registry Number | 16499725 |
| PubChem Substance ID | 253660095 |
| MDL Number | MFCD00192090 |
Specifications
| Appearance | White to Light yellow powder to crystal |
| Purity(Argentometric Titration) | min. 97.0 % |
Properties (reference)
| Melting Point | 160 °C(dec.) |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
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Application
Preparation of Gold(I)-Phosphine complexes
In a 20 mL screw-top vial is dissolved (SMe)2AuCl (C2719, 1.0 equiv) in CH2Cl2, and the resulting solution is cooled in an ice bath. A solution of the desired phosphine (D4501, 0.5 equiv) in CH2Cl2 is added dropwise, and the resulting solution is allowed to warm to room temperature and stirred for two hours. After TLC indicats complete consumption of the starting material, the reaction solution is concentrated in vacuo to yield the desired gold(I) complexes.
References
Application
Preparation of Gold(I)-NHC complexes
Ag2O (0.5 mmol) is added to a solution of the imidazolium ligand (1.0 mmol) in CH2Cl2. The suspension becomes clear after stirring 3 h at room temperature. Then a solution of Me2SAuCl (C2719, 1.0 mmol) in CH2Cl2 is added dropwise. The reaction mixture is stirred for another 4 h. Then the solution is filtered through Celite and the solvent is partially evaporated. Addition of hexane leads to the precipitation of the methiodides.
References
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Safety Data Sheet (SDS)
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Specifications
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