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CAS RN: 819050-89-0 | Product Number: B4549
Bis[rhodium(α,α,α',α'-tetramethyl-1,3-benzenedipropionic Acid)]
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![Bis[rhodium(α,α,α',α'-tetramethyl-1,3-benzenedipropionic Acid)]](/_ui/responsive/theme-tci/images/missing_product_zoom.jpg "Bis[rhodium(α,α,α',α'-tetramethyl-1,3-benzenedipropionic Acid)]")
Purity: >96.0%(HPLC)
Synonyms:
- Rh2(esp)2
Product Documents:
| Size | Unit Price | Saitama (Kawaguchi) | Hyogo (Amagasaki) | Stock in other WH |
Shipping Information
|
|---|---|---|---|---|---|
| 100MG |
¥13,000
|
≥60 | 18 | ≥100 |
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* The displayed price is the unit price and does not include consumption tax. The unit prices displayed are the latest and are subject to change without notice.
* To send your quote request for bulk quantities, please click on the "Request Bulk Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | B4549 |
| Purity / Analysis Method | >96.0%(HPLC) |
| Molecular Formula / Molecular Weight | C__3__2H__4__0O__8Rh__2 = 758.48 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive |
| Packaging and Container | 100MG-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 819050-89-0 |
| Reaxys Registry Number | 21493662 |
| PubChem Substance ID | 354333338 |
| MDL Number | MFCD08457636 |
Specifications
| Appearance | Yellow to Brown to Dark green powder to crystal |
| Purity(HPLC) | min. 96.0 area% |
Properties (reference)
GHS
Related Laws:
Transport Information:
Application
Synthesis of N-H Aziridines from Unactivated Olefins Using Hydroxylamine-O-Sulfonic Acid
Reference
- Direct and Stereospecific Synthesis of N-H and N-Alkyl Aziridines from Unactivated Olefins Using Hydroxylamine-O-Sulfonic Acids
Application
Synthesis of 1,2-Diamine Derivatives Using a Rhodium Catalyst
References
- Direct and Stereospecific Synthesis of N-H and N-Alkyl Aziridines from Unactivated Olefins Using Hydroxylamine-O-Sulfonic Acids
Application
Direct Synthesis of N-Unprotected Aziridines from Olefins Using a Rhodium Catalyst
Representative procedure: A round bottom flask is charged with alkene (0.5 mmol, 1.0 eq.) and CF3CH2OH (5 mL). To this solution at the specified temperature are added Rh2(esp)2 (3.8 mg, 5 µmol, 1 mol%) and 1 (0.119 g, 0.6 mmol, 1.2 eq.). The reaction is stirred at the specified temperature and monitored by TLC. More catalyst and 1 are added, if required. After completion, the reaction mixture is diluted with CH2Cl2(10 mL) and washed once with 15% aq. NaHCO3 solution (5 mL). The aqueous layer is extracted twice with CH2Cl2 (10 mL) and the combined organic portions are washed once with brine (5 mL), dried over Na2SO4, and concentrated in vacuo. The residue is purified on pre-packed SiO2 column.
References
- Direct Stereospecific Synthesis of Unprotected N-H and N-Me Aziridines from Olefins
PubMed Literature
Articles/Brochures
TCIMAIL
[Product Highlights] Synthesis of N-H Aziridines from Unactivated Olefins Using Hydroxylamine-O-Sulfonic Acid[Research Articles] Synthesis of 1,2-Diamine Derivatives Using a Rhodium Catalyst
[Research Articles] Direct Synthesis of N-Unprotected Aziridines from Olefins Using a Rhodium Catalyst
Product Documents (Note: Some products will not have analytical charts available.)
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Specifications
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