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CAS RN: 7583-90-6 | Product Number: A2558
1-Amino-2-methylpyridinium Iodide

Purity: >98.0%(T)(HPLC)
Synonyms:
Product Documents:
Size | Unit Price | Saitama (Kawaguchi) | Hyogo (Amagasaki) | Stock in other WH |
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1G |
¥9,000
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18 | 4 | Contact Us |
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* The displayed price is the unit price and does not include consumption tax. The unit prices displayed are the latest and are subject to change without notice.
* To send your quote request for bulk quantities, please click on the "Request Bulk Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
Product Number | A2558 |
Purity / Analysis Method | >98.0%(T)(HPLC) |
Molecular Formula / Molecular Weight | C__6H__9IN__2 = 236.06 |
Physical State (20 deg.C) | Solid |
Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
Store Under Inert Gas | Store under inert gas |
Condition to Avoid | Air Sensitive |
Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
CAS RN | 7583-90-6 |
Reaxys Registry Number | 3633876 |
PubChem Substance ID | 253660298 |
MDL Number | MFCD00955862 |
Specifications
Appearance | White to Light yellow powder to crystal |
Purity(HPLC) | min. 98.0 area% |
Purity(Nonaqueous Titration) | min. 98.0 % |
NMR | confirm to structure |
Properties (reference)
Melting Point | 152 °C(dec.) |
GHS
Pictogram |
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Signal Word | Warning |
Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
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Transport Information:
Application
Synthesis of N-Ylides
Experimental procedure: A solution of 1-amino-2-methylpyridinium iodide (3 mmol) and ethyl cyanoacetate (4 g, 35 mmol) in 50 mL of ethanol is stirred with K2CO3 (5 g) at room temperature for 3 days. The reaction mixture is then filtered to remove insoluble inorganic substances and the filtrate is concentrated under reduced pressure. The residue is separated by column chromatography (alumina) using ether and the CHCl3 as eluents to give the ylide 1 in 69 % yeild.
References
- Synthesis Using Pyridinium N-Ylides. I. Synthesis and Some Reactions of Substituted 1-(Acetylimino)pyridinium Ylides
PubMed Literature
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