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Organic Material with Photochemically Reversible Liquefaction and Solidification
No.163(October 2014)
1,2,3,4,5,6-Hexa-O-[11-[4-(4-hexylphenylazo)phenoxy]undecanoyl]-D-mannitol (1), developed by Akiyama, Yoshida, is a liquid-crystalline compound having a skeleton of sugar alcohol and azobenzene groups. 1 shows the photo-reactivity of liquefaction by UV light and solidification by visible light at room temperature, and can be repeatedly liquefied and solidified. The use of 1 is expected to apply to reusable photo-reversible adhesives.
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Liquefaction of the solid by UV light irradiation, and solidification by visible light irradiation (provided from AIST)
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View of photo-reversible adhesion and non-adhesion
*This product receives a license of invention of Advanced Industrial Science and Technology (AIST)
(Jpn. Patent Appl. 5360794).
If you use it for industrial purposes, please contact us.
References
- 1)H. Akiyama, M. Yoshida, Adv. Mater. 2012, 24, 2353.
- 2)H. Akiyama, M. Yoshida, National Institute of Advanced Industrial Science and Technology, Jpn. Kokai Tokkyo Koho 2011 256291, 2011.
- 3)H. Akiyama, M. Yoshida, National Institute of Advanced Industrial Science and Technology, PCT Int. Appl. WO 2013 168712, 2013.
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