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Asymmetric Double Aldol Reactions
No.106(April 2002)
The aldol reactions of the acetate esters 1 and a variety of aldehydes provide bis-aldol products via novel double aldol reactions with high diastereoselectivity, which has been reported by A. Abiko, S. Masamune et al. These products 2 serve as the starting materials for the synthesis of chiral triols 3 of C3 symmetry. Compounds of C3 symmetry have attracted much attention as valuable ligands for asymmetric catalysts.
References
- 1)Boron-mediated double aldol reaction of carboxylic esters
- 2)C3 Symmetry in asymmetric catalysis and chiral recognition
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