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p-Nitrophenyl Carbonate Monomer for Introduction of Functional Moieties into Polymers and Monomers
2-(p-Nitrophenoxycarbonyloxy)ethyl Methacrylate (1) is a methacrylate monomer that reacts with primary amino groups to introduce functional moieties via a urethane linkage. In addition to its use in the synthesis of functional monomers,1) 1 can also be used to introduce functional moieties into (co)polymers derived from 1,2-5) providing an advantageous approach to incorporating functional groups that are not compatible with polymerization conditions. Furthermore, since 1 is applicable to polymer synthesis by atom transfer radical polymerization (ATRP) or reversible addition-fragmentation chain transfer (RAFT) polymerization, it has been used to develop therapeutic nanoparticles by incorporating compounds such as the anti-tumor drug doxorubicin,3) dopamine coordinating to iron ions,3,4) and DFO coordinating to 89Zr,5) into block copolymers composed of 1.
Related Products
- N1293
- 2-(p-Nitrophenoxycarbonyloxy)ethyl Methacrylate
- A0305
- Dopamine Hydrochloride
- S0814
- N-Succinimidyl Acrylate
- S0812
- N-Succinimidyl Methacrylate
References
- 1) Synthesis and Thermo-/pH- Dual Responsive Properties of Poly(amidoamine) Dendronized Poly(2-hydroxyethyl) Methacrylate
- 2) Functional and reactive polymethacrylates suitable for preparation of peptide/protein–polymer conjugates
- 3) Enhanced Antitumor Efficacy by a Cascade of Reactive Oxygen Species Generation and Drug Release
- 4) Protein-Delivering Nanocomplexes with Fenton Reaction-Triggered Cargo Release to Boost Cancer Immunotherapy
- 5) Gadolinium Metallofullerene-Based Activatable Contrast Agent for Tumor Signal Amplification and Monitoring of Drug Release
