text.skipToContent text.skipToNavigation

TCI uses cookies to personalize and improve your user experience. By continuing on our website, you accept the use of cookies. You can change or update your cookiesettings at any time.

Maximum quantity allowed is 999

Please select the quantity

Products > TCI Topics Archives > TCI Topics 2016 >

Decarboxylative silylation of α,β-unsaturated carboxylic acids

Liu et al. have reported a decarboxylative silylation of α,β-unsaturated carboxylic acids. According to their report, the decarboxylative C-Si bond-forming reaction of trans-cinnamic acid with triphenylsilane successfully proceeds in the presence of copper chloride(I) as a reaction initiator and tert-butyl hydroperoxide (TBHP). This reaction can be applied to α,β-alkenyl- and α,β-alkynyl- carboxylic acids giving the corresponding vinyl- and alkynyl- silanes. This is the first example of the decarboxylative silylation of carboxylic acids. The reaction pathway is suggested to proceed through a radical pathway initiated by SET (single electron transfer) from a copper salt.

C0353,T0661

References

Page Top

Session Status
Your session will timeout in 10 minutes. You will be redirected to the HOME page after session timeout. Please click the button to continue session from the same page. minute. You will be redirected to the HOME page after session timeout. Please click the button to continue session from the same page.
Continue Operation
Your session has timed out. You will be redirected to the HOME page.
Close
TCI
Please enter the required fields (*)
Please enter valid mobile number
New User? *
Add me to your mailing list *

Cancel

Thank you for signing up!


New subscribers will get FREE TCI Gifts!
We will notify you of further updates on our New products, Offers, Schemes, Discounts, etc.

OK