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CAS RN: 1109-15-5 | Product Number: T2313
Tris(pentafluorophenyl)borane
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Purity: >98.0%(NMR)
Size | Unit Price | Hyderabad | Japan* | Quantity |
---|---|---|---|---|
1G |
₹9,400.00
|
3 | ≥100 |
|
5G |
₹25,400.00
|
3 | ≥60 |
|
*Upon orders receipt, Hyderabad stocks will be dispatched on the same day.
*Items available in Japan warehouse will be dispatched in 10-12 working days.
*INR price is exclusive of domestic taxes applicable.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
Product Number | T2313 |
Purity / Analysis Method | >98.0%(NMR) |
Molecular Formula / Molecular Weight | C__1__8BF__1__5 = 511.98 |
Physical State (20 deg.C) | Solid |
Storage Temperature | Frozen (<0°C) |
Store Under Inert Gas | Store under inert gas |
Condition to Avoid | Hygroscopic,Heat Sensitive |
Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
CAS RN | 1109-15-5 |
Reaxys Registry Number | 2931347 |
PubChem Substance ID | 87558752 |
Merck Index (14) | 9755 |
MDL Number | MFCD00269813 |
Appearance | White to Gray to Brown powder to crystal |
Purity(NMR) | min. 98.0 atom% |
Water | max. 1.0 % |
Melting Point | 128 °C |
Maximum Absorption Wavelength | 306 nm (Toluene) |
Solubility (soluble in) | Toluene |
Pictogram |
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Signal Word | Warning |
Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
References
- B(C6F5)3‑Catalyzed Regioselective Deuteration of Electron-Rich Aromatic and Heteroaromatic Compounds
References
- By-Product-Free Siloxane-Bond Formation and Programmed One-Pot Oligosiloxane Synthesis
References
- Heterolytic dihydrogen activation with the 1,8-bis(diphenylphosphino)naphthalene/B(C6F5)3 pair and its application for metal-free catalytic hydrogenation of silyl enol ether
In a glove box, a Schlenk tube is charged with an alkene (0.300 mmol). In two vials are weighed B(C6F5)3 (7.7 mg, 15 µmol) and tri(cyclohexa-2,5-dien-1-yl)silane (1, 28.0 mg, 0.105 mmol). All the sealed containers are taken out of the glove box, and the Schlenk tube is connected to a N2 line. Under a N2 counterflow are subsequently added 0.3 mL of CH2Cl2, 1 then B(C6F5)3. The tube is completely sealed and stirred at room temperature for 24 h. After this time, two drops of triethylamine are added to the solution under an N2 counterflow, and the resulting mixture is stirred for 5 min before being filtered over a short alumina column (elution with CH2Cl2). After evaporation of all volatiles, the crude product is purified by flash column chromatography to give the multisubstituted silane 3.
References
- Formal SiH4 chemistry using stable and easy-to-handle surrogates
References
- T. Mahdi, D. W. Stephan, J. Am. Chem. Soc. 2014, 136, 15809.
- Highlighted in Chem. Eng. News 2014, 92 (44), 8.
References
- 1)T. Mahdi, Z. M. Heiden, S. Grimme, D. W. Stephan, J. Am. Chem. Soc. 2012, 134, 4088.
- 2)D. W. Stephan, G. Erker, Angew. Chem., Int. Ed. 2010, 49, 46.
References
Articles/Brochures
[Product Highlights] A Bisphosphine Usable for Metal-free Hydrogenations
[Research Articles] High Throughput Sequence-controlled Oligosiloxane Synthesis
[Research Articles] Tri(cyclohexa-2,5-dien-1-yl)silane: A Stable and Easy-to-handle Surrogate of Monosilane (SiH4)
[Research Articles] Metal-Free Hydrogenation of Ketone by Frustrated Lewis Pairs (FLPs)
[Research Articles] Metal-Free Hydrogenation of N-Phenyl Aromatic Rings
[Research Articles] Metal-Free Hydrogenation of Imines Catalyzed by B(C6F5)3
Safety Data Sheet (SDS)
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Specifications
C of A & Other Certificates
Sample C of A
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Analytical Charts
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