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CAS RN: 294-90-6 | Product Number: T1874
1,4,7,10-Tetraazacyclododecane
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Purity: >97.0%(GC)(T)
Synonyms:
- Cyclen
Product Documents:
| Size | Unit Price | Hyderabad | Japan* | Quantity |
|---|---|---|---|---|
| 1G |
₹20,800.00
|
3 | ≥40 |
|
| 5G |
₹23,400.00
|
4 | ≥100 |
|
*Upon orders receipt, Hyderabad stocks will be dispatched on the same day.
*Items available in Japan warehouse will be dispatched in 10-12 working days.
*INR price is exclusive of domestic taxes applicable.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | T1874 |
| Purity / Analysis Method | >97.0%(GC)(T) |
| Molecular Formula / Molecular Weight | C__8H__2__0N__4 = 172.28 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Hygroscopic |
| CAS RN | 294-90-6 |
| Reaxys Registry Number | 606114 |
| PubChem Substance ID | 87558626 |
Specifications
| Appearance | White to Almost white powder to crystal |
| Purity(GC) | min. 97.0 % |
| Purity(Neutralization titration) | min. 97.0 % |
| Melting point | 110.0 to 114.0 °C |
Properties (reference)
| Melting Point | 111 °C |
| Solubility in water | Soluble |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H302 + H312 : Harmful if swallowed or in contact with skin. H314 : Causes severe skin burns and eye damage. H410 : Very toxic to aquatic life with long lasting effects. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P273 : Avoid release to the environment. P260 : Do not breathe dusts or mists. P270 : Do not eat, drink or smoke when using this product. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P391 : Collect spillage. P362 + P364 : Take off contaminated clothing and wash it before reuse. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P405 : Store locked up. |
Related Laws:
| RTECS# | XA5253000 |
Transport Information:
| UN Number | UN3259 |
| Class | 8 |
| Packing Group | II |
Application
Cyclen-catalyzed Henry reaction (nitroaldol reaction)
Typical procedure: Nitromethane (122 mg) is added to the solution of benzaldehyde (106 mg) in THF (1 mL). Then, cyclen (8.6 mg) is added. The solution is stirred at room temperature for 24 h. Volatile components are removed under reduced pressure and the residue is purified by chromatography on silica gel (eluent: pentane/diethyl ether) to give 2-nitro-1-phenylethanol (134 mg, 80 %).
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