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CAS RN: 5518-52-5 | Product Number: T1643

Tri(2-furyl)phosphine


Purity: >98.0%(GC)
Synonyms:
  • TFP
Product Documents:
1G
₹5,400.00
3   ≥60 
5G
₹16,900.00
2   39  

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Product Number T1643
Purity / Analysis Method >98.0%(GC)
Molecular Formula / Molecular Weight C__1__2H__9O__3P = 232.17 
Physical State (20 deg.C) Solid
Storage Temperature Room Temperature (Recommended in a cool and dark place, <15°C)
CAS RN 5518-52-5
Reaxys Registry Number 1577564
PubChem Substance ID 87577384
SDBS (AIST Spectral DB) 9360
MDL Number

MFCD00151857

Specifications
Appearance White to Yellow to Orange powder to crystal
Purity(GC) min. 98.0 %
Melting point 61.0 to 65.0 °C
Properties (reference)
Melting Point 63 °C
Boiling Point 136 °C/4 mmHg
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
Related Laws:
Transport Information:
Application
Stereoselective synthesis of cis-3,5-disubstituted morpholines

Typical procedure: A dried Schlenk tube is charged with Pd(OAc)2 (2.3 mg), tri(2-furyl)phosphine (9.3 mg), and NaOtBu (96.1 mg) under nitrogen. The tube is evacuated and backfilled with nitrogen, then 2-bromotoluene (171 mg) and a solution of (–)-(S)-N-[1-(allyloxy)-3-phenylpropane-2-yl]aniline (134 mg) in toluene (1.25 mL) are added to the tube. The mixture is heated to 105 °C for 18 h with stirring. The reaction mixture is cooled to rt, quenched with saturated aqueous NH4Cl (3 mL), and extracted with EtOAc (3 mL x 3). The combined organic layers are concentrated in vacuo and the crude product is purified by flash chromatography on silica gel (eluent: 5 % EtOAc/hexanes). This procedure gives (–)-(3S,5R)-3-benzyl-5-(2-methylbenzyl)-4-phenylmorpholine (121 mg, 68 %).

References


PubMed Literature


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