Maximum quantity allowed is 999
Please select the quantity
CAS RN: 26628-22-8 | Product Number: S0489
Sodium Azide
×
![]()
×
Purity: >99.0%(T)
Synonyms:
Product Documents:
| Size | Unit Price | Hyderabad | Japan* | Quantity |
|---|---|---|---|---|
| 100G |
₹3,400.00
|
11 | ≥100 |
|
*Upon orders receipt, Hyderabad stocks will be dispatched on the same day.
*Items available in Japan warehouse will be dispatched in 10-12 working days.
*INR price is exclusive of domestic taxes applicable.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | S0489 |
| Purity / Analysis Method | >99.0%(T) |
| Molecular Formula / Molecular Weight | NaN__3 = 65.01 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 26628-22-8 |
| Reaxys Registry Number | 1209320 |
| PubChem Substance ID | 87558449 |
| Merck Index (14) | 8581 |
| MDL Number | MFCD00003536 |
Specifications
| Appearance | White to Almost white powder to crystaline |
| Purity(Cerium redox Method) | min. 99.0 % |
Properties (reference)
| Solubility in water | Soluble |
| Degree of solubility in water | 417 g/l 17 °C |
| Solubility (slightly sol. in) | Ethanol |
| Solubility (insoluble in) | Ether |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H300 + H310 : Fatal if swallowed or in contact with skin. H314 : Causes severe skin burns and eye damage. H370 : Causes damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H373 : May cause damage to organs through prolonged or repeated exposure. H410 : Very toxic to aquatic life with long lasting effects. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P273 : Avoid release to the environment. P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P262 : Do not get in eyes, on skin, or on clothing. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P391 : Collect spillage. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. P361 + P364 : Take off immediately all contaminated clothing and wash it before reuse. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P405 : Store locked up. |
Related Laws:
| RTECS# | JY8050000 |
Transport Information:
| UN Number | UN1687 |
| Class | 6.1 |
| Packing Group | II |
Application
TCI Practical Example: Tetrazole ring building reaction
-
Used Chemicals
-
Procedure
-
Sodium azide (139 mg, 2.14 mmol, 1.3 eq.) in toluene (3 mL) was added to a solution of 4-bromobenzonitrile (300 mg, 1.65 mmol) and triethylamine hydrochloride (295 mg, 2.14 mmol, 1.3 eq.) at room temperature. The mixture was stirred at 100 °C for 4 hours. Triethylamine hydrochloride (295 mg, 2.14 mmol, 1.3 eq.) and sodium azide (139 mg, 2.14 mmol, 1.3 eq.) were added and stirred overnight at the same temperature. Then the reaction mixture was quenched with water (15 mL) and the aqueous layer was washed with ethyl acetate (15 mL x 2) and was removed under reduced pressure and the residue was purified by column chromatography (on silica gel, dichloromethane:methanol = 5:1) and washed with acetonitrile:water (1:1, 6 mL) to give 5-(4-bromophenyl)-1H-tetrazole as a white solid (240 mg, 65% yield).
-
Experimenter’s Comments
-
The reaction mixture was monitored by UPLC.
The reaction was performed in a fume hood because hydrogen azide may be generated.
-
Analytical Data
-
5-(4-Bromophenyl)-1H-tetrazole
1H NMR (400 MHz, CDCl3); δ 7.99 (d, J = 8.0 Hz, 2H), 7.84 (d, J = 8.0 Hz, 2H).
-
Lead Reference
-
- (S)-5-PYRROLIDIN-2-YL-1H-TETRAZOLE
Application
Versatile Azidation Reagent
References
PubMed Literature
Articles/Brochures
TCIMAIL
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.
The requested SDS is not available.
Please Contact Us for more information.
Specifications
C of A & Other Certificates
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
Sample C of A
This is a sample C of A and may not represent a recently manufactured lot of the product.
A sample C of A for this product is not available at this time.
Analytical Charts
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
The requested analytical chart is not available. Sorry for the inconvenience.