Published TCIMAIL newest issue No.197 | New tool "TCI SpectraViewer" | [Product Highlights] o-Nitrobenzyl Photolabile... | Product Document Searching Made Easy by 2D Code!
Maximum quantity allowed is 999
CAS RN: 7697-37-2 | Product Number: N0806
Nitric Acid (67%)
Purity:
Size | Unit Price | Hyderabad | Japan* | Quantity |
---|---|---|---|---|
300ML |
₹2,700.00
|
3 | ≥100 |
|
*Upon orders receipt, Hyderabad stocks will be dispatched on the same day.
*Items available in Japan warehouse will be dispatched in 10-12 working days.
*INR price is exclusive of domestic taxes applicable.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
Product Number | N0806 |
Molecular Formula / Molecular Weight | HNO__3 = 63.01 |
Physical State (20 deg.C) | Liquid |
Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
Condition to Avoid | Light Sensitive |
CAS RN | 7697-37-2 |
Reaxys Registry Number | 3587310 |
Merck Index (14) | 6577 |
MDL Number | MFCD00011349 |
Appearance | Colorless clear liquid |
Concentration(Neutralization titration) | min. 67.5 w/w% |
Boiling Point | 121 °C |
Specific Gravity (20/20) | 1.41 |
Solubility in water | Completely miscible |
Pictogram | |
Signal Word | Danger |
Hazard Statements | H330 : Fatal if inhaled. H314 : Causes severe skin burns and eye damage. H370 : Causes damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H304 : May be fatal if swallowed and enters airways. H272 : May intensify fire; oxidizer. H290 : May be corrosive to metals. |
Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P220 : Keep/Store away from clothing/ combustible materials. P210 : Keep away from heat. P234 : Keep only in original container. P221 : Take any precaution to avoid mixing with combustibles. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 : Wear respiratory protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P390 : Absorb spillage to prevent material damage. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P310 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 : Wash contaminated clothing before reuse. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. P406 : Store in corrosive resistant container with a resistant inner liner. P405 : Store locked up. |
RTECS# | QU5900000 |
UN Number | UN2031 |
Class | 8 / 5.1 |
Packing Group | II |
-
Used Chemicals
-
Procedure
-
A solution of 3',4'-dimethoxyacetophenone (5.00 g, 27.7 mmol) in acetic acid (13 mL) was added dropwise to a solution of nitric acid (100 mL) and acetic acid (20 mL) at 0 °C. After stirring for 6 hours, the reaction mixture was poured into iced water (1000 mL) and the crystallized solid was filtered off. The solid was washed with ethanol to afford 1 (3.66 g, 58% yield) as a light yellow powder.
-
Experimenter’s Comments
-
The reaction mixture was monitored by TLC (dichloromethane:ethyl acetate = 18:1, Rf = 0.69) and UPLC.
-
Analytical Data
-
Compound 1
1H NMR (400 MHz, CDCl3); δ 7.61 (s, 1H), 6.76 (s, 1H), 3.98 (s, 6H), 2.50 (s, 3H).
-
Lead Reference
-
- Triggering a [2]Rotaxane Molecular Shuttle by a Photochemical Bond-Cleavage Strategy
Articles/Brochures
Safety Data Sheet (SDS)
The requested SDS is not available.
Please Contact Us for more information.
Specifications
C of A & Other Certificates
Sample C of A
A sample C of A for this product is not available at this time.
Analytical Charts
The requested analytical chart is not available. Sorry for the inconvenience.