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CAS RN: 7697-37-2 | Product Number: N0806

Nitric Acid (67%)


Purity:
Synonyms:
Product Documents:
300ML
₹2,700.00
3   ≥100 

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Product Number N0806
Molecular Formula / Molecular Weight HNO__3 = 63.01 
Physical State (20 deg.C) Liquid
Storage Temperature Room Temperature (Recommended in a cool and dark place, <15°C)
Condition to Avoid Light Sensitive
CAS RN 7697-37-2
Reaxys Registry Number 3587310
Merck Index (14) 6577
MDL Number

MFCD00011349

Specifications
Appearance Colorless clear liquid
Concentration(Neutralization titration) min. 67.5 w/w%
Properties (reference)
Boiling Point 121 °C
Specific Gravity (20/20) 1.41
Solubility in water Completely miscible
GHS
Pictogram Pictogram Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H330 : Fatal if inhaled.
H314 : Causes severe skin burns and eye damage.
H370 : Causes damage to organs.
H372 : Causes damage to organs through prolonged or repeated exposure.
H304 : May be fatal if swallowed and enters airways.
H272 : May intensify fire; oxidizer.
H290 : May be corrosive to metals.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P270 : Do not eat, drink or smoke when using this product.
P220 : Keep/Store away from clothing/ combustible materials.
P210 : Keep away from heat.
P234 : Keep only in original container.
P221 : Take any precaution to avoid mixing with combustibles.
P271 : Use only outdoors or in a well-ventilated area.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P284 : Wear respiratory protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P390 : Absorb spillage to prevent material damage.
P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P301 + P310 : IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P363 : Wash contaminated clothing before reuse.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
P406 : Store in corrosive resistant container with a resistant inner liner.
P405 : Store locked up.
Related Laws:
RTECS# QU5900000
Transport Information:
UN Number UN2031
Class 8 / 5.1
Packing Group II
Application
TCI Practical Example: Nitration Using Nitric Acid

TCI Practical Example: Nitration Using Nitric Acid

Used Chemicals

Procedure

A solution of 3',4'-dimethoxyacetophenone (5.00 g, 27.7 mmol) in acetic acid (13 mL) was added dropwise to a solution of nitric acid (100 mL) and acetic acid (20 mL) at 0 °C. After stirring for 6 hours, the reaction mixture was poured into iced water (1000 mL) and the crystallized solid was filtered off. The solid was washed with ethanol to afford 1 (3.66 g, 58% yield) as a light yellow powder.

Experimenter’s Comments

The reaction mixture was monitored by TLC (dichloromethane:ethyl acetate = 18:1, Rf = 0.69) and UPLC.

Analytical Data

Compound 1

1H NMR (400 MHz, CDCl3); δ 7.61 (s, 1H), 6.76 (s, 1H), 3.98 (s, 6H), 2.50 (s, 3H).

Lead Reference


PubMed Literature


TCIMAIL
Product Documents (Note: Some products will not have analytical charts available.)
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