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CAS RN: 18173-64-3 | Product Number: B5499

tert-Butyldimethylsilanol


Purity: >95.0%(GC)
Synonyms:
Product Documents:
5ML
₹8,400.00
4   ≥40 
25ML
₹22,000.00
8   17  

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Product Number B5499
Purity / Analysis Method >95.0%(GC)
Molecular Formula / Molecular Weight C__6H__1__6OSi = 132.28 
Physical State (20 deg.C) Liquid
Storage Temperature Room Temperature (Recommended in a cool and dark place, <15°C)
Store Under Inert Gas Store under inert gas
Condition to Avoid Moisture Sensitive
CAS RN 18173-64-3
Reaxys Registry Number 1732777
PubChem Substance ID 354334613
MDL Number

MFCD00010673

Specifications
Appearance Colorless to Almost colorless clear liquid
Purity(GC) min. 95.0 %
Properties (reference)
Boiling Point 139 °C
Flash point 45 °C
Specific Gravity (20/20) 0.84
Refractive Index 1.42
GHS
Pictogram Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H226 : Flammable liquid and vapor.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P240 : Ground/bond container and receiving equipment.
P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 : Keep container tightly closed.
P243 : Take precautionary measures against static discharge.
P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 : Use only non-sparking tools.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
P403 + P235 : Store in a well-ventilated place. Keep cool.
Related Laws:
Transport Information:
UN Number UN1987
Class 3
Packing Group III
Application
t-Butyldimethylsilylation of Alcohols using TBS Reagents

B5499

References

  • A New Method for Silylation of Hydroxylic Compounds: Reaction of Phenols and Alcohols with Silanols Mediated by Diethyl Azodicarboxylate and Triphenylphosphine
  • Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols
    • P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.


PubMed Literature


Product Documents (Note: Some products will not have analytical charts available.)
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