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CAS RN: 247129-85-7 | Product Number: B3958
(2-Bromoethyl)diphenylsulfonium Trifluoromethanesulfonate
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Purity: >98.0%(T)(HPLC)
Synonyms:
- (2-Bromoethyl)diphenylsulfonium Triflate
Product Documents:
| Size | Unit Price | Hyderabad | Japan* | Quantity |
|---|---|---|---|---|
| 1G |
₹4,200.00
|
2 | ≥40 |
|
| 5G |
₹13,400.00
|
1 | ≥100 |
|
*Upon orders receipt, Hyderabad stocks will be dispatched on the same day.
*Items available in Japan warehouse will be dispatched in 10-12 working days.
*INR price is exclusive of domestic taxes applicable.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | B3958 |
| Purity / Analysis Method | >98.0%(T)(HPLC) |
| Molecular Formula / Molecular Weight | C__1__5H__1__4BrF__3O__3S__2 = 443.29 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 247129-85-7 |
| Reaxys Registry Number | 8458234 |
| PubChem Substance ID | 172089093 |
| MDL Number | MFCD12546049 |
Specifications
| Appearance | White to Almost white powder to crystal |
| Purity(HPLC) | min. 98.0 area% |
| Purity(Argentometric Titration) | min. 98.0 % |
| Melting point | 88.0 to 92.0 °C |
Properties (reference)
| Melting Point | 90 °C |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
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Transport Information:
Application
An Efficient Vinyl Sulfonium Salt Precursor for the Synthesis of Imidazolinium Salts
Typical Procedure (R1 = R2 = 2,6-diisopropylphenyl) : (2-Bromoethyl)diphenylsulfonium Trifluoromethanesulfonate (610 mg, 1.38 mmol) is added to a stirred solution of N,N’-bis(2,6-diisopropylphenyl)formamidine (400 mg, 1.10 mmol) and diisopropylethylamine (0.48 mL, 2.75 mmol) in 8 mL of anhydrous MeCN under a nitrogen atmosphere. After refluxing for 1.5 h, the mixture is cooled to rt and the solvent is reduced to half in volume by nitrogen overflow. Ether is added and the mixture is stirred until a precipitate formed. The precipitate is collected by filtration and washed in the following order: Hot (100-110 °C) toluene (1-4 mL), diethyl ether (3 mL), water (1-4 mL) and diethyl ether (3 mL). Then it is dried in vacuo to give 1,3-bis(2,6-diisopropylphenyl)imidazolinium trifluoromethanesulfonate (532 mg, 90%) as an amorphous powder.
References
- S. P. Fritz, Synlett 2012, 23, 480.
- E. M. McGarrigle, S. P. Fritz, L. Favereau, M. Yar, V. K. Aggarwal, Org. Lett. 2011, 13, 3060.
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