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Langmuir-Blodgett (LB) Film Forming Reagents
Recently, the Langmuir-Blodgett Method1) is receiving much attention as a means to obtaining functional organic super thin films in the electric field. This method can control rearrangement in molecular dimensions while retaining highly orderly structure. New diversified applications utilizing the method are being developed in a variety of fields such as molecular electronics, bioelectronics, etc.2) Amphiphilic diacetylene monocarboxylic acids are readily polymerised by heat, light3) and radiation while polymerized films3,4) are thermally and mechanically stable. As a result, application to photoresist material5) having a high degree of resolving power and nonlinear optical material6) are expected.
Literature
- 1)K. B. Blodgett, J. Am. Chem. Soc. 1935, 57, 1007.
- 2)(a) M. Sugi, et al., Oyo Butsuri 1983, 52, 567.
- (b) M. Sugi, Hyomen Kagaku (J. Surf. Sci. Soc. Jpn.) 1985, 6, 102.
- (c) K. Fukuda, et al., in LB Films and Electronics, CMC, 1986.
- (d) Review: Maku (Membrane) 1986, 11(3).
- (e) Review: Hyomen Kagaku (j. Surf. Sci. Soc. Jpn.) 1986, 7(6).
- (b) M. Sugi, Hyomen Kagaku (J. Surf. Sci. Soc. Jpn.) 1985, 6, 102.
- 3)(a) B. Tieke, G. Wegner, D. Naegele, H. Ringsdorf, Angew. Chem., Int. Ed. Engl. 1976, 15, 764.
- 4)(a) D. Day, J. B. Lando, Macromolecules 1980, 13, 1478.
- (b) I. R. Perterson, IEE Proceeding Pt I 1983, 130, 252.
- (b) I. R. Perterson, IEE Proceeding Pt I 1983, 130, 252.
- 5)(a) A. Barraud, et al., Solid State Technology 1979, 22, 120.
- 6)(a) F. Kajzar, J. Messier, J. Zyss, I. Ledoux, Opt. Commun. 1983, 45, 133.