Maintenance Notice (4:30 AM - 11:00 AM December 21, 2024): This website is scheduled to be unavailable due to maintenance. We appreciate your patience and understanding.
Published TCIMAIL newest issue No.197
Maximum quantity allowed is 999
Please select the quantity
Optically Active Ketoiminato Co(II) Complexes for Enantioselective Borohydride Reduction
No.126(August 2007)
The ketoiminato cobalt(II) complexes 1 and 2 developed by Mukaiyama, Yamada and co-workers are utilized for catalytic asymmetric reductions. The asymmetric reduction using 1 and 2 can use sodium borohydride, a widely used reducing agent. Therefore, this method is receiving much attention as it is likely to become a popular, convenient and economical method for obtaining optically active alcohols, amines, 1,3-diols, 3-hydroxycarbonyl compounds, β-substituted amides and so forth.
References
- 1)Applications of MPAC
- K. D. Sugi, T. Nagata, T. Yamada, T. Mukaiyama, Chem. Lett. 1997, 26, 493.
- S. Kezuka, T. Mita, N. Ohtsuki, T. Ikeno, T. Yamada, Chem. Lett. 2000, 29, 824.
- T. Mukaiyama, K. D. Sugi, T. Nagata, T. Yamada, WO 98039276 (Mitsui Chemicals Inc.).
- K. D. Sugi, T. Nagata, T. Yamada, T. Mukaiyama, Chem. Lett. 1997, 26, 493.
- 2)Applications of AMAC
- Y. Ohtsuka, K. Koyasu, T. Ikeno, T. Yamada, Org. Lett. 2001, 3, 2543.
- Y. Ohtsuka, K. Koyasu, D. Miyazaki, T. Ikeno, T. Yamada, Org. Lett. 2001, 3, 3421.
- M. Sato, Y. Gunji, T. Ikeno, T. Yamada, Synthesis 2004, 1434.
- T. Nagata, T. Yamada, WO 02038535 (Mitsui Chemicals Inc.).
- Y. Ohtsuka, K. Koyasu, T. Ikeno, T. Yamada, Org. Lett. 2001, 3, 2543.
- 3)Reviews
The prices are subject to change without notice. Please confirm the newest price by our online catalog before placing an order.
In addition, sales products changes with areas. Please understand that a product is not available when the product details page is not displayed.
In addition, sales products changes with areas. Please understand that a product is not available when the product details page is not displayed.