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CAS RN: 51901-85-0 | Product Number: B2132

B-Bromocatecholborane


Purity: >97.0%(T)
Synonyms:
  • 2-Bromo-1,3,2-benzodioxaborole
Product Documents:
5G
€84.00
2   ≥40 
25G
€294.00
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Product Number B2132
Purity / Analysis Method >97.0%(T)
Molecular Formula / Molecular Weight C__6H__4BBrO__2 = 198.81 
Physical State (20 deg.C) Solid
Storage Temperature Refrigerated (0-10°C)
Store Under Inert Gas Store under inert gas
Condition to Avoid Light Sensitive,Moisture Sensitive,Heat Sensitive
CAS RN 51901-85-0
Reaxys Registry Number 2445073
PubChem Substance ID 87565000
MDL Number

MFCD00013341

Specifications
Appearance White to Amber to Dark purple powder to lump
Purity(Argentometric Titration) min. 97.0 %
Properties (reference)
Melting Point 52 °C
Boiling Point 76 °C/9 mmHg
GHS
Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H314 : Causes severe skin burns and eye damage.
H228 : Flammable solid.
Precautionary Statements P260 : Do not breathe dust.
P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
Related Laws:
Transport Information:
UN Number UN2925
Class 4.1 / 8
Packing Group III
HS Number 2934999090
Application
Deprotection of MOM Groups/methylenation in Dichloromethane using B-Bromocatecholborane
References

Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols

P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.


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