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Published TCIMAIL newest issue No.197
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CAS RN: 667-27-6 | Product Number: B1463
Ethyl Bromodifluoroacetate
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Purity: >98.0%(GC)
Synonyms:
- Bromodifluoroacetic Acid Ethyl Ester
Product Documents:
| Size | Unit Price | Belgium | Japan* |
|---|---|---|---|
| 5G |
€16.00
|
3 | ≥100 |
| 25G |
€30.00
|
7 | ≥80 |
| 250G |
€188.00
|
1 | ≥100 |
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | B1463 |
| Purity / Analysis Method | >98.0%(GC) |
| Molecular Formula / Molecular Weight | C__4H__5BrF__2O__2 = 202.98 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 667-27-6 |
| Reaxys Registry Number | 1906095 |
| PubChem Substance ID | 87564380 |
| SDBS (AIST Spectral DB) | 18950 |
| MDL Number | MFCD00042069 |
Specifications
| Appearance | Colorless to Light yellow to Light orange clear liquid |
| Purity(GC) | min. 98.0 % |
Properties (reference)
| Boiling Point | 113 °C |
| Flash point | 21 °C |
| Specific Gravity (20/20) | 1.57 |
| Refractive Index | 1.39 |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H314 : Causes severe skin burns and eye damage. H225 : Highly flammable liquid and vapour. |
| Precautionary Statements | P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. |
Related Laws:
| EC Number | 211-567-0 |
Transport Information:
| UN Number | UN2924 |
| Class | 3 / 8 |
| Packing Group | II |
| HS Number | 2915907098 |
Application
α,α-Difluoro Reformatsky Reagent
References
- A. Furstner, Synthesis 1989, 571.
- R. J. Linderman, D. M. Graves, J. Org. Chem. 1989, 54, 661.
- idem., Tetrahedron Lett. 1987, 28, 4259.
- T. Taguchi, O. Kitagawa, Y. Suda, S. Ohkawa, A. Hashimoto, Y. Iitaka, Y. Kobayashi, Tetrahedron Lett. 1988, 29, 5291.
- L. W. Hertel, J. S. Kroin, J. W. Misner, J. M. Tustin, J. Org. Chem. 1988, 53, 2406.
- D. Schirlin, S. Baltzer, J. M. Altenburger, Tetreahedron Lett. 1988, 29, 3687.
PubMed Literature
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