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CAS RN: 2923-18-4 | Product Number: T1336
Sodium Trifluoroacetate
Purity: >98.0%(T)
Synonyms:
- Trifluoroacetic Acid Sodium Salt
Product Documents:
Size | Unit Price | Same Day | 2-3 Business Days |
---|---|---|---|
25G |
$25.00
|
16 | ≥100 |
100G |
$73.00
|
5 | 23 |
500G |
$211.00
|
18 | 19 |
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Product Number | T1336 |
Purity / Analysis Method | >98.0%(T) |
Molecular Formula / Molecular Weight | C__2F__3NaO__2 = 136.00 |
Physical State (20 deg.C) | Solid |
Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
Store Under Inert Gas | Store under inert gas |
Condition to Avoid | Hygroscopic |
CAS RN | 2923-18-4 |
Reaxys Registry Number | 3597949 |
PubChem Substance ID | 87577105 |
MDL Number | MFCD00013217 |
Specifications
Appearance | White to Almost white powder to crystal |
Purity(Nonaqueous Titration) | min. 98.0 % |
Solubility in Water | very faint turbidity |
Water | max. 2.0 % |
Properties (reference)
Melting Point | 207 °C(dec.) |
Solubility in water | Soluble |
Degree of solubility in water | 625 g/l 20 °C |
GHS
Related Laws:
RTECS# | AK0250000 |
Transport Information:
H.S.code* | 2915.90-000 |
Application
Trifluoromethylation of Aromatic Halides
Typical Procedure (Entry 1):
A mixture of iodobenzene (5 mmol), sodium trifluoroacetate (20 mmol), and copper (I) iodide (10 mmol) in N-methylpyrrolidone (NMP) (40 mL) is heated under argon atmosphere. Evolution of CO2 begins at around 140 ℃. After 4 h stirring at 160 ℃, the resulting mixture is diluted with diethylether - hexane (1 : 1), filtrated through celite layer, washed with water (3 times), and dried over MgSO4. By means of GC measurement of the solution, the yield of (trifluoromethyl)benzene is determined as 72%.
A mixture of iodobenzene (5 mmol), sodium trifluoroacetate (20 mmol), and copper (I) iodide (10 mmol) in N-methylpyrrolidone (NMP) (40 mL) is heated under argon atmosphere. Evolution of CO2 begins at around 140 ℃. After 4 h stirring at 160 ℃, the resulting mixture is diluted with diethylether - hexane (1 : 1), filtrated through celite layer, washed with water (3 times), and dried over MgSO4. By means of GC measurement of the solution, the yield of (trifluoromethyl)benzene is determined as 72%.
References
- A convenient trifluoromethylation of aromatic halides with sodium trifluoroacetate
Application
Difluorocarbene Precursor
Reference
- Sodium Trifluoroacetate: an Efficient Difluorocarbene Precursor for Alkenes
PubMed Literature
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