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CAS RN: 18173-64-3 | Product Number: B5499
tert-Butyldimethylsilanol
Purity: >95.0%(GC)
Synonyms:
Product Documents:
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Product Number | B5499 |
Purity / Analysis Method | >95.0%(GC) |
Molecular Formula / Molecular Weight | C__6H__1__6OSi = 132.28 |
Physical State (20 deg.C) | Liquid |
Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
Store Under Inert Gas | Store under inert gas |
Condition to Avoid | Moisture Sensitive |
CAS RN | 18173-64-3 |
Reaxys Registry Number | 1732777 |
PubChem Substance ID | 354334613 |
MDL Number | MFCD00010673 |
Specifications
Appearance | Colorless to Almost colorless clear liquid |
Purity(GC) | min. 95.0 % |
Properties (reference)
Boiling Point | 139 °C |
Flash point | 45 °C |
Specific Gravity (20/20) | 0.84 |
Refractive Index | 1.42 |
GHS
Pictogram | |
Signal Word | Warning |
Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H226 : Flammable liquid and vapor. |
Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P240 : Ground/bond container and receiving equipment. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 : Keep container tightly closed. P243 : Take precautionary measures against static discharge. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 : Use only non-sparking tools. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P403 + P235 : Store in a well-ventilated place. Keep cool. |
Related Laws:
Transport Information:
UN Number | UN1987 |
Class | 3 |
Packing Group | III |
H.S.code* | 2931.90-000 |
Application
t-Butyldimethylsilylation of Alcohols using TBS Reagents
References
- A New Method for Silylation of Hydroxylic Compounds: Reaction of Phenols and Alcohols with Silanols Mediated by Diethyl Azodicarboxylate and Triphenylphosphine
- Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols
- P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.
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