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Chiral Bis-hydroxamic Acid Ligands for Asymmetric Epoxidations

Advantages

• Useful ligand for asymmetric expoxidation
• High yield and ee in the asymmetric epoxidation of allyl, homoallyl, and bishomoallyl alcohols
• Water-free conditions are not required for the epoxidation of allyl alcohols.

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Applications

Vanadium-Catalyzed Asymmetric Epoxidation 1)

Vanadium-Catalyzed Asymmetric Epoxidation

Zirconium(IV) or Hafnium(IV)-Catalyzed Asymmetric Epoxidation 2)

Zirconium(IV) or Hafnium(IV)-Catalyzed Asymmetric Epoxidation

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References

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