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CAS RN: 7550-45-0 | Product Number: T3238
Titanium(IV) Chloride (ca. 19% in Toluene, ca. 1.0mol/L)
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Purity:
Synonyms:
- Titanium Tetrachloride (ca. 19% in Toluene, ca. 1.0mol/L)
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 100ML |
£34.00
|
2 | 15 |
|
| 500ML |
£101.00
|
Contact Us | 8 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
Supplemental Product Information:
This product cannot be shipped to Russia and Turkey.
| Product Number | T3238 |
| Molecular Formula / Molecular Weight | TiCl__4 = 189.67 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive,Heat Sensitive |
| CAS RN | 7550-45-0 |
| Reaxys Registry Number | 3903207 |
| PubChem Substance ID | 253660643 |
| Merck Index (14) | 9478 |
| MDL Number | MFCD00011267 |
Specifications
| Appearance | Light yellow to Yellow to Orange clear liquid |
| Concentration(Argentometric titration) | 19.0 to 22.0 w/w% |
Properties (reference)
| Flash point | 8 °C |
| Specific Gravity (20/20) | 0.96 |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H301 + H331 : Toxic if swallowed or if inhaled. H314 : Causes severe skin burns and eye damage. H370 : Causes damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H335 : May cause respiratory irritation. H361d : Suspected of damaging the unborn child. H304 : May be fatal if swallowed and enters airways. H225 : Highly flammable liquid and vapour. |
| Precautionary Statements | P260 : Do not breathe mist or vapours. P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P201 : Obtain special instructions before use. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. |
Related Laws:
| EC Number | 231-441-9 |
Transport Information:
| UN Number | UN3286 |
| Class | 3 / 6.1,8 |
| Packing Group | II |
| HS Number | 2827398590 |
Application
TCI Practical Example: McMurry Coupling with Titanium(IV) Chloride
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Used Chemicals
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Procedure
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A suspension of benzophenone (500 mg, 2.7 mmol) and zinc (540 mg, 8.2 mmol) in dried THF (30 mL) was stirred under nitrogen at 0 ℃. TiCl4 (ca. 19% in toluene, ca. 1.0 mol/L) (5.5 mL, 5.5 mmol) was dropwised for 10 min. The ice bath was removed and the mixture was stirred at 70 ℃ for 30 min. The reaction was quenched with aqueous solution of potassium carbonate and extracted with ethyl acetate. The organic phase was dried over anhydrous sodium sulfate and filtered. The solvent was removed under reduced pressure and the crude product was washed with hexane to give tetraphenylethylene (1) as a white solid (314 mg, y. 69%).
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Experimenter’s Comments
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The reaction mixture was monitored by TLC (hexane:dichloromethane = 4:1, Rf = 0.48).
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Analytical Data
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Tetraphenylethylene (1)
1H NMR (270 MHz, CDCl3); δ 7.12-7.08 (m, 4H), 7.04-7.01 (m, 16H).
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Lead Reference
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- Dissipative aggregation-induced emission behaviour of an amino-functionalized tetraphenylethene using a pH oscillator
PubMed Literature
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Specifications
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Other Documents
Related Products
Titanium(IV) Chloride (14% in Dichloromethane, ca. 1.0mol/L)
| Product # | T2052 |
| CAS RN | 7550-45-0 |
| Purity / Analysis Method: |