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CAS RN: 29892-37-3 | Product Number: C2719
Chloro(dimethylsulfide)gold(I)
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Purity: >97.0%(T)
Synonyms:
- (Dimethylsulfide)gold(I) Chloride
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 200MG |
£52.00
|
2 | 7 |
|
| 1G |
£221.00
|
5 | ≥100 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | C2719 |
| Purity / Analysis Method | >97.0%(T) |
| Molecular Formula / Molecular Weight | C__2H__6AuClS = 294.55 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Light Sensitive,Air Sensitive,Heat Sensitive |
| CAS RN | 29892-37-3 |
| Reaxys Registry Number | 16499725 |
| PubChem Substance ID | 253660095 |
| MDL Number | MFCD00192090 |
Specifications
| Appearance | White to Light yellow powder to crystal |
| Purity(Argentometric Titration) | min. 97.0 % |
Properties (reference)
| Melting Point | 160 °C(dec.) |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
Related Laws:
Transport Information:
| HS Number | 2843300000 |
Application
Preparation of Gold(I)-Phosphine complexes
In a 20 mL screw-top vial is dissolved (SMe)2AuCl (C2719, 1.0 equiv) in CH2Cl2, and the resulting solution is cooled in an ice bath. A solution of the desired phosphine (D4501, 0.5 equiv) in CH2Cl2 is added dropwise, and the resulting solution is allowed to warm to room temperature and stirred for two hours. After TLC indicats complete consumption of the starting material, the reaction solution is concentrated in vacuo to yield the desired gold(I) complexes.
References
Application
Preparation of Gold(I)-NHC complexes
Ag2O (0.5 mmol) is added to a solution of the imidazolium ligand (1.0 mmol) in CH2Cl2. The suspension becomes clear after stirring 3 h at room temperature. Then a solution of Me2SAuCl (C2719, 1.0 mmol) in CH2Cl2 is added dropwise. The reaction mixture is stirred for another 4 h. Then the solution is filtered through Celite and the solvent is partially evaporated. Addition of hexane leads to the precipitation of the methiodides.
References
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