Published TCIMAIL newest issue No.196
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CAS RN: 1802-30-8 | Product Number: B3502
2,2'-Bipyridine-5,5'-dicarboxylic Acid
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Purity: >98.0%(GC)(T)
Synonyms:
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 1G |
£38.00
|
1 | ≥100 |
|
| 5G |
£114.00
|
3 | ≥100 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | B3502 |
| Purity / Analysis Method | >98.0%(GC)(T) |
| Molecular Formula / Molecular Weight | C__1__2H__8N__2O__4 = 244.21 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 1802-30-8 |
| Reaxys Registry Number | 214282 |
| PubChem Substance ID | 125307614 |
| MDL Number | MFCD01318320 |
Specifications
| Appearance | White to Orange to Green powder to crystal |
| Purity(GC) | min. 98.0 % |
| Purity(Neutralization titration) | min. 98.0 % |
Properties (reference)
| Melting Point | 365 °C |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
Related Laws:
Transport Information:
| HS Number | 2933399990 |
Application
Preparing for Iridium-Organic Unit of Photoredox-active MOF
A mixture of H2dcbpy [B3502] (2 mmol, 0.5 g) and Ir2(ppy)4Cl2 [D5744] (1 mmol, 1 g) is dissolved in CH3OH (100 mL). Excessive Na2CO3 is added to the reaction mixture and then heated to reflux under stirring for 5 h. After cooling to room temperature, the solvent is removed under rotary evaporation. Deionized water is added to dissolve the precipitation by stirring, and the complex is achieved by the addition of hydrochloric acid, and then filtered and dried (82% yield based on Ir).
References
- A Dynamic Entangled Framework Based on an Iridium-Organic Unit Showing Reversible Luminescence Turn-on Sensing
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