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Published TCIMAIL newest issue No.197
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Sulfene Equivalent
No.135(July 2008)
Compound 1 reacts with bases such as Et3N and produces disulfene 2. This compound 2 easily reacts with diene compounds to form [4+2] cycloadduct 3. Therefore, the compound 2 can be used as a trapping reagent for diene compounds because of this property.1) In addition, the compound 2 also reacts with α-olefins to form γ-chloroalkanesulfonyl chloride.2)
References
- 1)[4+2] Cycloaddition reaction of dienes with sulfenes
- 2)Sulfonylation of alkenes
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