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CAS RN: 16853-85-3 | Product Number: L0203
Lithium Aluminum Hydride (Powder)
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Purity: >95.0%(T)
Synonyms:
- LAH (Powder)
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 25G |
97,00 €
|
16 | ≥40 |
|
| 100G |
343,00 €
|
7 | ≥80 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | L0203 |
| Purity / Analysis Method | >95.0%(T) |
| Molecular Formula / Molecular Weight | LiAlH__4 = 37.95 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive |
| CAS RN | 16853-85-3 |
| Reaxys Registry Number | 11460447 |
| PubChem Substance ID | 87560001 |
| Merck Index (14) | 350 |
| MDL Number | MFCD00011075 |
Specifications
| Appearance | White to Gray powder to crystal |
| Purity(NBS Method) | min. 95.0 % |
Properties (reference)
| Melting Point | 125 °C(dec.) |
| Solubility (soluble in) | Tetrahydrofuran, Ether, Dioxane |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H330 : Fatal if inhaled. H301 : Toxic if swallowed. H314 : Causes severe skin burns and eye damage. H260 : In contact with water releases flammable gases which may ignite spontaneously. |
| Precautionary Statements | P260 : Do not breathe dust. P231 + P232 : Handle and store contents under inert gas. Protect from moisture. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P302 + P335 + P334 : IF ON SKIN: Brush off loose particles from skin. Immerse in cool water. P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. |
Related Laws:
| EC Number | 240-877-9 |
| RTECS# | BD0100000 |
Transport Information:
| UN Number | UN1410 |
| Class | 4.3 |
| Packing Group | I |
| HS Number | 2850002090 |
Application
Reducing Agent
References
- Communications Reduction of Acetals to Ethers by Means of Lithium Aluminum Hydride-Aluminum Chloride
- Selective reductions. 28. The fast reaction of lithium aluminum hydride with alkyl halides in tetrahydrofuran. A reappraisal of the scope of the reaction
- Asymmetric synthesis via axially dissymmetric molecules. 6. Rational designing of efficient chiral reducing agents. Highly enantioselective reduction of aromatic ketones by binaphthol-modified lithium aluminum hydride reagents
Application
Inorganic Hydride Used as A Hydrogen Sources of Fuel Cell
References
- Design for the cold start-up of a man-portable fuel cell and hydrogen storage system
- Development of hydrogen storage for fuel cell generators. I: Hydrogen generation using hydrolysis of hydrides
- Hydrogen generation from hydrides in millimeter scale reactors for micro proton exchange membrane fuel cell applications
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