Published TCIMAIL newest issue No.197
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New Oxidation of Alcohols
No.116(April 2003)
Triarylbismuth dichloride (1) is a pentavalent organobismuth compound developed by Matano et al., which can oxidize alcohols to aldehydes and ketones under mild conditions. The oxidation reaction using 1 proceeds, in the presence of a base, with high yields and high chemoselectivity. 1 is recognized as a very effective oxidizing agent with great ease of use since bismuth is regarded as an element of low toxicity and because 1 is stable at room temperature.
References
- 1)Y. Matano, H. Nomura, Angew. Chem. Int. Ed. 2002, 41, 3028.
- 2)Tokyo Kasei Kogyo Co. Ltd. JP Pat. Appl. 2001-337065.
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