Lead Acetate Anhydrous Forming Perovskite under Anhydrous Condition

No.176(January 2018)

L0315: Lead(II) Acetate [for Perovskite precursor] (1)

Perovskite solar cells have received much attention due to their increased efficiency, and are anticipated to be fabricated at lower costs in the future. The light absorbing layer in the solar cell consists of lead perovskites. It is well known that high quality perovskite precursor boosts the solar cell efficiency with reproducibility.¹⁾ Recently, the use of a lead acetate precursor was reported for several perovskite researches. Anhydrous lead acetate (1) allows for dry perovskite solar cell production, although lead acetate trihydrate is typically what is available. Lead acetate affords fast crystal growth of perovskites, and provides ultrasmooth pin-hole free perovskite film.^2-7)

Scheme 1. Proposed formation mechanism of CH₃NH₃PbI₃ from Pb(OAc)₂²⁾

References

1)Reproducible fabrication of efficient perovskite-based solar cells: X-ray crystallographic studies on the formation of CH₃NH₃PbI₃ layers
- A. Wakamiya, M. Endo, T. Sasamori, N. Tokitoh, Y. Ogomi, S. Hayase, Y. Murata, Chem. Lett. 2014, 43, 711.
2)PCE >10%: Effect of different lead precursors on perovskite solar cell performance and stability
- F. K. Aldibaja, L. Badia, E. Mas-Marzá, R. S. Sánchez, E. M. Barea, I. Mora-Sero, J. Mater. Chem. A 2015, 3, 9194.
3)PCE >17%: High performance perovskite solar cell via multi-cycle low temperature processing of lead acetate precursor solutions
- T. Singh, T. Miyasaka, Chem. Commun. 2016, 52, 4784.
4)PCE 14%: Ultrasmooth organic-inorganic perovskite thin-film formation and crystallization for efficient planar heterojunction solar cells
- W. Zhang, M. Saliba, D. T. Moore, S. K. Pathak, M. T. Hörantner, T. Stergiopoulos, S. D. Stranks, G. E. Eperon, J. A. Alexander-Webber, A. Abate, A. Sadhanala, S. Yao, Y. Chen, R. H. Friend, L. A. Estroff, U. Wiesner, H. J. Snaith, Nat. Commun. 2015, 6, 6142.
5)PCE >18%: High-performance inverted planar heterojunction perovskite solar cells based on lead acetate precursor with efficiency exceeding 18%
- L. Zhao, D. Luo, J. Wu, Q. Hu, W. Zhang, K. Chen, T. Liu, Y. Liu, Y. Zhang, F. Liu, T. P. Russell, H. J. Snaith, R. Zhu, Q. Gong, Adv. Funct. Mater. 2016, 26, 3508.
6)PCE >13%: Pinhole-free perovskite films for efficient solar modules
- W. Qiu, T. Merckx, M. Jaysankar, C. Masse de la Huerta, L. Rakocevic, W. Zhang, U. W. Paetzold, R. Gehlhaar, L. Froyen, J. Poortmans, D. Cheyns, H. J. Snaith, P. Heremans, Energy Environ. Sci. 2016, 9, 484.
7)PCE >14%: Chlorine incorporation for enhanced performance of planar perovskite solar cell based on lead acetate precursor
- J. Qing, H.-T. Chandran, Y.-H. Cheng, X.-K. Liu, H.-W. Li, S.-W. Tsang, M.-F. Lo, C.-S. Lee, ACS Appl. Mater. Interfaces 2015, 7, 23110.

Related Compounds

L0279: Lead(II) Iodide (99.99%, trace metals basis) [for Perovskite precursor]
L0288: Lead(II) Bromide [for Perovskite precursor]
L0291: Lead(II) Chloride (purified by sublimation) [for Perovskite precursor]
L0292: Lead(II) Chloride [for Perovskite precursor]
M2556: Methylamine Hydroiodide (MAI), (Water <100 ppm) [for Perovskite precursor]
F0974: Formamidine Hydroiodide (FAI), (Water <100 ppm) [for Perovskite precursor]

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Lead Acetate Anhydrous Forming Perovskite under Anhydrous Condition

References

Related Compounds

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