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for Cross-Coupling Reaction

No.106(April 2002)
T1794
Tri-n-butylvinyltin (1)
Tri-n-butylvinyltin 1 reacts with organic electrophiles such as acid halides1) and vinyl triflates2) in the presence of palladium catalyst, and introduces a vinyl group into the electrophiles in high yield. Furthermore, 1 also readily undergoes palladium catalyzed cross-coupling reactions with hypervalent iodine compounds under mild conditions3).

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