用于合成共价有机框架(COF)的2,2'-联吡啶衍生物

[2,2'-联吡啶]-5,5'-二甲醛 (1)和[2,2'-联吡啶]-5,5'-二胺 (2)是联吡啶的衍生物，可以用于共价有机框架(COF)的合成。COF是结晶状多孔材料，由于它们的多孔性和明确的周期性结构，有望广泛用于催化剂、气体吸附和气体分离等领域。此外，利用1或2，通过联吡啶位点与金属原子配位，或使用1,2-二溴乙烷进行联吡啶的季铵化，可以开发功能性COF。例如，水电解中析氧反应的催化剂¹⁾、析氢反应的光催化剂²⁾和光热转换材料³⁾已有报道。

关键词

B6576

[2,2'-联吡啶]-5,5'-二甲醛

D2893

[2,2'-联吡啶]-5,5'-二胺

D0180

1,2-二溴乙烷

文献

• 1) Regulating the Synergistic Effect in Bimetallic Two-Dimensional Polymer Oxygen Evolution Reaction Catalysts by Adjusting the Coupling Strength Between Metal Centers
  • D. Fa, J. Yuan, G. Feng, S. Lei, W. Hu, Angew. Chem. Int. Ed. 2023, 62, e202300532.
• 2) Integrating Light-Harvesting Ruthenium(II)-based Units into Three-Dimensional Metal Covalent Organic Frameworks for Photocatalytic Hydrogen Evolution
  • W.-K. Han, Y. Liu, X. Yan, Y. Jiang, J. Zhang, Z.-G. Gu, Angew. Chem. Int. Ed. 2022, 61, e202208791.
• 3) Stable Radical Cation-Containing Covalent Organic Frameworks Exhibiting Remarkable Structure-Enhanced Photothermal Conversion
  • Z. Mi, P. Yang, R. Wang, J. Unruangsri, W. Yang, C. Wang, J. Guo, J. Am. Chem. Soc. 2019, 141, 14433.

相关产品分类页

• Covalent Organic Frameworks (COFs) Linkers

TCI精选产品

• Covalent Organic Frameworks (COFs) Linkers

返回页首