Published TCIMAIL newest issue No.196
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CAS RN: 15418-29-8 | Product Number: T2666
Tetrakis(acetonitrile)copper(I) Tetrafluoroborate
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Purity: >98.0%(T)
Synonyms:
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 1G |
20,00 €
|
6 | ≥100 |
|
| 5G |
64,00 €
|
12 | ≥100 |
|
| 25G |
204,00 €
|
1 | 19 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | T2666 |
| Purity / Analysis Method | >98.0%(T) |
| Molecular Formula / Molecular Weight | C__8H__1__2BCuF__4N__4 = 314.56 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive |
| CAS RN | 15418-29-8 |
| Reaxys Registry Number | 4925687 |
| PubChem Substance ID | 87561637 |
| MDL Number | MFCD09265110 |
Specifications
| Appearance | White to Almost white powder to crystal |
| Purity(Potassium permanganate method) | min. 98.0 % |
Properties (reference)
| Melting Point | 164 °C(dec.) |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H302 : Harmful if swallowed. H314 : Causes severe skin burns and eye damage. |
| Precautionary Statements | P260 : Do not breathe dust. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. |
Related Laws:
Transport Information:
| UN Number | UN1759 |
| Class | 8 |
| Packing Group | III |
| HS Number | 2926907090 |
Application
DABSO as a SO2 Source Usable for Direct Sulfonylative-Suzuki Coupling of Aryl Boronic Acids
Reference
- Copper(I)-catalyzed Sulfonylative Suzuki?Miyaura Cross-coupling
Application
Copper-Catalyzed Radical Cyclization of Aryl Amines
Typical Procedure (X = Cl, Y = O, n = 1, R1, R2 and R3 = H):
To a dried Schlenk-tube containing 2-(allyloxy)aniline (0.5 mmol, 74.6 mg, 1 eq.), tert-butyl nitrite (0.55 mmol, 56.7 mg, 1.1 eq.) in acetone (5.0 mL) at 0 °C, Cu(CH3CN)4BF4 (0.05 mmol, 15.7 mg) and conc. HCl aq (2.5 eq.) are added. The reaction mixture is warmed to room temperature and stirred for 3 h. After completion, most of the solvent is removed in vacuo and the residue is purified by flash chromatography on silica gel (eluent: pentane) to afford 3-(chloromethyl)-2,3-dihydrobenzofuran as a colorless oil (0.46 mmol, 77.6 mg, 92% yield).
To a dried Schlenk-tube containing 2-(allyloxy)aniline (0.5 mmol, 74.6 mg, 1 eq.), tert-butyl nitrite (0.55 mmol, 56.7 mg, 1.1 eq.) in acetone (5.0 mL) at 0 °C, Cu(CH3CN)4BF4 (0.05 mmol, 15.7 mg) and conc. HCl aq (2.5 eq.) are added. The reaction mixture is warmed to room temperature and stirred for 3 h. After completion, most of the solvent is removed in vacuo and the residue is purified by flash chromatography on silica gel (eluent: pentane) to afford 3-(chloromethyl)-2,3-dihydrobenzofuran as a colorless oil (0.46 mmol, 77.6 mg, 92% yield).
References
PubMed Literature
Articles/Brochures
TCIMAIL
[Product Highlights] DABSO as a SO2 Source Usable for Direct Sulfonylative-Suzuki Coupling of Aryl Boronic Acids[Research Articles] Copper-Catalyzed Radical Cyclization of Aryl Amines
Product Documents (Note: Some products will not have analytical charts available.)
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