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Published TCIMAIL newest issue No.197
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CAS RN: 309-88-6 | Product Number: H0598
Ishikawa's Reagent [Fluorinating Reagent]
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![Ishikawa's Reagent [Fluorinating Reagent]](/_ui/responsive/theme-tci/images/missing_product_zoom.jpg "Ishikawa's Reagent [Fluorinating Reagent]")
Purity: >92.0%(T)
Synonyms:
- Hexafluoropropene Diethylamine
- N,N-Diethyl-1,1,2,3,3,3-hexafluoropropylamine
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 25G |
€68.00
|
1 | ≥100 |
|
| 100G |
€188.00
|
13 | ≥40 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | H0598 |
| Purity / Analysis Method | >92.0%(T) |
| Molecular Formula / Molecular Weight | C__7H__1__1F__6N = 223.16 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive |
| CAS RN | 309-88-6 |
| Reaxys Registry Number | 7833073 |
| PubChem Substance ID | 87570980 |
| Merck Index (14) | 5108 |
| MDL Number | MFCD00060264 |
Specifications
| Appearance | Colorless to Yellow clear liquid |
| Purity(Neutralization titration) | min. 92.0 % |
Properties (reference)
| Boiling Point | 54 °C/50 mmHg |
| Flash point | 40 °C |
| Specific Gravity (20/20) | 1.23 |
| Solubility (soluble in) | Acetone, Ether |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H314 : Causes severe skin burns and eye damage. H226 : Flammable liquid and vapour. |
| Precautionary Statements | P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. |
Related Laws:
Transport Information:
| UN Number | UN2920 |
| Class | 8 / 3 |
| Packing Group | II |
| HS Number | 2921199990 |
Application
Ishikawa’s Reagent: A Stable Fluorinating Reagent
Experimental procedure: A solution of Ishikawa's reagent (13 g, 60 mmol) in diethyl ether (50 mL) is dropped into a solution of 1-octanol (6.5 g, 50 mmol) in diethyl ether (30 mL) at 0-5 °C. After stirring for 4 h, the reaction mixture is thrown into water and extracted with diethyl ether. The extract is washed with water, dried over magnesium sulfate, and evaporated to remove the solvent. The residue is distilled to give 1-fluorooctane (5.4 g, 82%), bp 145-146 °C.
References
- F-Propene-Dialkylamine Reaction Products as Fluorinating Agents
PubMed Literature
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
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