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CAS RN: 16605-03-1 | Product Number: D4825
3-(Diphenylphosphino)-1-propylamine
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Purity: >95.0%(GC)(T)
Synonyms:
- (3-Aminopropyl)diphenylphosphine
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 200MG |
€63.00
|
Contact Us | 20 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | D4825 |
| Purity / Analysis Method | >95.0%(GC)(T) |
| Molecular Formula / Molecular Weight | C__1__5H__1__8NP = 243.29 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive |
| CAS RN | 16605-03-1 |
| Reaxys Registry Number | 2730850 |
| PubChem Substance ID | 253661468 |
| MDL Number | MFCD00233832 |
Specifications
| Appearance | Colorless to Light yellow to Light orange clear liquid |
| Purity(GC) | min. 95.0 % |
| Purity(Neutralization titration) | min. 95.0 % |
Properties (reference)
| Boiling Point | 145 °C/1 mmHg |
| Flash point | 170 °C |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H314 : Causes severe skin burns and eye damage. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. |
Related Laws:
Transport Information:
| UN Number | UN2735 |
| Class | 8 |
| Packing Group | II |
| HS Number | 2931499090 |
Application
Synthesis of the P,N-Chelated Palladium Complex Useful for the Suzuki-Miyaura Cross Coupling Reactions
Experimental procedure: A solution of 3-(diphenylphosphino)-1-propylamine (0.13 g, 0.52 mmol) in CH2Cl2 (2.0 mL) is added dropwise to a suspended solution of Na2PdCl4 (0.076 g, 0.26 mmol) in CH2Cl2 (25 mL) and the reaction mixture is stirred at ambient temperature for 2 h. After the reaction, the volume is reduced to ca. 7 mL and diethyl ether is added to precipitate a whitish powder which is then filtered off and washed with diethyl ether and recrystallized from acetone–dichloromethane. The complex 1 is obtained in 87% yield.
References
- The air-stable and highly efficient P,N-chelated palladium(II) complexes as catalysts for the Suzuki cross-coupling reaction at room temperature
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