Maintenance Notice (4:30 AM - 11:00 AM December 21, 2024): This website is scheduled to be unavailable due to maintenance. We appreciate your patience and understanding.
Published TCIMAIL newest issue No.197
Maximum quantity allowed is 999
Bitte wählen Sie die Menge aus.
New Palladacycle Precatalyst
No.156(January 2013)
Di-μ-chlorobis(2'-amino-1,1'-biphenyl-2-yl-C,N)dipalladium(II) (1) is a palladacycle dimer formed from two aminobiphenyl-pallacycle units structurally bridged by two chlorine atoms.1) 1 is a palladacycle precatalyst and by the use of 1 with various phosphine ligands can be used as a catalyst for Suzuki-Miyaura cross-coupling.2) As an example, when a catalyst prepared from 1 and 1,1'-bis(diisopropylphosphino)ferrocene (dippf) is employed, couplings of benzyloxymethyltrifluoroborate with aromatic mesyl esters successfully proceed to afford the desired coupling products.2a)
References
- The cyclopalladation reaction of 2-phenylaniline revisited
- Suzuki–Miyaura cross-coupling using 1 as a palladacycle precatalyst
The prices are subject to change without notice. Please confirm the newest price by our online catalog before placing an order.
In addition, sales products changes with areas. Please understand that a product is not available when the product details page is not displayed.
In addition, sales products changes with areas. Please understand that a product is not available when the product details page is not displayed.