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CAS RN: 15243-33-1 | Product Number: T2181

Triruthenium Dodecacarbonyl


Purity:
Synonyms:
  • Ruthenium Carbonyl
Product Documents:
100MG
$72.00
1   Contact Us 5  
1G
$334.00
1   1   23  

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Product Number T2181
Molecular Formula / Molecular Weight C__1__2O__1__2Ru__3 = 639.33 
Physical State (20 deg.C) Solid
Storage Temperature Room Temperature (Recommended in a cool and dark place, <15°C)
Packaging and Container 100MG-Glass Bottle with Plastic Insert (View image),  1G-Glass Bottle with Plastic Insert (View image)
CAS RN 15243-33-1
Reaxys Registry Number 14281346
PubChem Substance ID 87558750
MDL Number

MFCD00011209

Specifications
Appearance Orange to Brown powder to crystal
Elemental analysis(Carbon) 22.00 to 23.00 %
Properties (reference)
Melting Point 145 °C(dec.)
Maximum Absorption Wavelength 393(EtOAc) nm
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H332 : Harmful if inhaled.
Precautionary Statements P261 : Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P271 : Use only outdoors or in a well-ventilated area.
P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
Related Laws:
Transport Information:
HS Number 2931.90.9052
Application
Stereodivergent Ruthenium-Catalyzed Transfer Semihydrogenation of Diaryl Alkynes

Typical procedure (R = Ph): Diphenylacetylene (89 mg), Ru3(CO)12 (9.6 mg), PPh3 (6.6 mg), Acetic acid (46 mg), H2O (18 mg) and DMF (1 mL) are placed in a 25 mL thick-walled tube under a flow of nitrogen. The tube is heated at 145 °C with stirring for 24 h. The reaction mixture is cooled to rt and is purified by silica gel column chromatography (eluent: cyclohexane) to give (Z)-stilbene (84 mg, 93 %) with the selectivity of 96 % (GC). When TFA (85.5 mg) is employed, the reaction is carried out using Ru3(CO)12 (3.2 mg) at 145 °C for 3 h, and the reaction mixture is worked up as above to give (E)-stilbene (81.8 mg, 91 %) with the selectivity of >99 % (GC).

References


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