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CAS RN: 912823-79-1 | Product Number: P1626
Pentafluoroanilinium Trifluoromethanesulfonate
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Purity: >98.0%(T)(HPLC)
Synonyms:
- Pentafluoroanilinium Triflate
- (Pentafluorophenyl)ammonium Trifluoromethanesulfonate
- PFPAT
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 1G |
$69.00
|
1 | 2 | ≥100 |
|
| 5G |
$206.00
|
2 | 1 | ≥40 |
|
| 25G |
$622.00
|
1 | 1 | 13 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
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*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | P1626 |
| Purity / Analysis Method | >98.0%(T)(HPLC) |
| Molecular Formula / Molecular Weight | C__7H__3F__8NO__3S = 333.15 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 912823-79-1 |
| Reaxys Registry Number | 15026764 |
| PubChem Substance ID | 87558623 |
Specifications
| Appearance | White to Light yellow to Dark green powder to crystal |
| Purity(HPLC) | min. 98.0 area% |
| Purity(Neutralization titration) | min. 98.0 % |
Properties (reference)
| Solubility in water | Soluble |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H314 : Causes severe skin burns and eye damage. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P260 : Do not breathe dusts or mists. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 : Wash contaminated clothing before reuse. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P405 : Store locked up. |
Related Laws:
Transport Information:
| UN Number (DOT-AIR) | UN1759 |
| Class (DOT-AIR) | 8 |
| Packing Group (TCI-A) | III |
| HS Number | 2921.49.5000 |
Application
Efficient Method for the Catalytic Esterification using Ammonium Triflate Catalyst
References
- Y. Tanabe, T. Misaki, H. Iida, Y. Arai, Yuki Gosei Kagaku Kyokaishi (J. Synth. Org. Chem., Jpn.) 2004, 62, 1249.
- T. Funatomi, K. Wakasugi, T. Misaki, Y. Tanabe, Green Chemistry, 2006, 8, 1022.
Application
Synthesis of Bis-indolyl Methane Derivatives Using PFPAT Catalyst
Typical Procedure:
A mixture of aldehyde (1 mmol), indole (2 mmol) dissolved in acetonitrile (3 mL), and PFPAT (10 mol%) is stirred for appropriate reaction time. The reaction is monitored by TLC. The organic phase is washed with 1 M NaOH aqueous solution (1 mL). The separated organic phase is evaporated under reduced pressure to give a crude product, which is purified by distillation or by column chromatography (hexane–ethyl acetate).
A mixture of aldehyde (1 mmol), indole (2 mmol) dissolved in acetonitrile (3 mL), and PFPAT (10 mol%) is stirred for appropriate reaction time. The reaction is monitored by TLC. The organic phase is washed with 1 M NaOH aqueous solution (1 mL). The separated organic phase is evaporated under reduced pressure to give a crude product, which is purified by distillation or by column chromatography (hexane–ethyl acetate).
References
PubMed Literature
Articles/Brochures
TCIMAIL
[TCIMAIL No.138] Useful Ammonium Triflate Catalysts for Esterification[Research Articles] Synthesis of Bis-indolyl Methane Derivatives Using PFPAT Catalyst
Product Documents (Note: Some products will not have analytical charts available.)
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Specifications
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