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CAS RN: 12135-22-7 | Product Number: P1528

Palladium Hydroxide (contains Pd, PdO) on Carbon (wetted with ca. 50% Water)


Purity:
Synonyms:
  • Pearlman's Catalyst (contains Pd, PdO) (wetted with ca. 50% Water)
Product Documents:
10G
$463.00
1   3   ≥100 
50G
$2,303.00
2   1   35  

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Supplemental Product Information:

This product is a heterogeneous catalyst containing palladium hydroxide supported on activated carbon. It is wetted and the palladium content equals about 20% per dried substance.

Product Number P1528
Molecular Formula / Molecular Weight Pd(OH)__2 = 140.43 
Physical State (20 deg.C) Solid
Storage Temperature Room Temperature (Recommended in a cool and dark place, <15°C)
Store Under Inert Gas Store under inert gas
Condition to Avoid Air Sensitive
CAS RN 12135-22-7
Reaxys Registry Number 11342936
PubChem Substance ID 87558562
Merck Index (14) 7060
MDL Number

MFCD00064599

Specifications
Appearance Black powder to crystal
Drying loss 45.0 to 60.0 %
Properties (reference)
Solubility in water Insoluble
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P302 + P352 : IF ON SKIN: Wash with plenty of soap and water.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
P362 : Take off contaminated clothing and wash before reuse.
Related Laws:
Transport Information:
HS Number 2825.90.9000
Application
Hydrogenation using Pearlman's Catalyst : Cleavage of Bn Group

P1528

P1528

Reference

  • Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols
    • P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.


Application
Deprotection of BOM Groups using Pearlman's Catalyst

P1528

Reference

  • Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols
    • P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.


PubMed Literature


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