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CAS RN: 87413-09-0 | Product Number: D2045
Dess-Martin Periodinane
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Purity: >95.0%(T)
Synonyms:
- 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one
- DMP
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 1G |
$35.00
|
2 | 1 | 4 |
|
| 5G |
$106.00
|
7 | 3 | 30 |
|
| 25G |
$293.00
|
6 | 2 | 13 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
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*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
Supplemental Product Information:
This product may generate a little insoluble matter overtime while storing.
Since no effect the reaction, please filtering as needed before use.
| Product Number | D2045 |
| Purity / Analysis Method | >95.0%(T) |
| Molecular Formula / Molecular Weight | C__1__3H__1__3IO__8 = 424.14 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Frozen (-20°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Light Sensitive,Air Sensitive,Moisture Sensitive,Heat Sensitive |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 87413-09-0 |
| Reaxys Registry Number | 4548207 |
| PubChem Substance ID | 87568496 |
| Merck Index (14) | 2933 |
| MDL Number | MFCD00130127 |
Specifications
| Appearance | White to Almost white powder to crystal |
| Purity(Iodometric Titration) | min. 95.0 % |
| NMR | confirm to structure |
Properties (reference)
| Melting Point | 124 °C(dec.) |
| Solubility (soluble in) | Chloroform, Acetone |
| Solubility (slightly sol. in) | Ether |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H341 : Suspected of causing genetic defects. H272 : May intensify fire; oxidizer. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P202 : Do not handle until all safety precautions have been read and understood. P220 : Keep/Store away from clothing/ combustible materials. P210 : Keep away from heat. P201 : Obtain special instructions before use. P221 : Take any precaution to avoid mixing with combustibles. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P308 + P313 : IF exposed or concerned: Get medical advice/ attention. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302 + P352 : IF ON SKIN: Wash with plenty of soap and water. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P362 : Take off contaminated clothing and wash before reuse. P405 : Store locked up. |
Related Laws:
Transport Information:
| UN Number (DOT-AIR) | UN1479 |
| Class (DOT-AIR) | 5.1 |
| Packing Group (TCI-A) | III |
| HS Number | 2931.90.6000 |
Application
TCI Practical Example: Mild Oxidation Using Dess-Martin Periodinane
Used Chemicals
Procedure
To dichloromethane (10 mL) was added trans-2-phenyl-1-cyclohexanol (0.30 g，1.7 mmol) and DMP (0.72 g, 1.7 mmol) at room temperature. The reaction mixture was stirred overnight at room temperature, then diluted with diethyl ether and washed with saturated aqueous sodium bicarbonate, 10% aqueous sodium thiosulfate, water and brine. The organic layer was concentrated under reduced pressure. The resulting crude product was purified by column chromatography (hexane:ethyl acetate = 8:1 on silica gel) to give 1 as a white solid (0.22 g, 74% yield).
Experimenter’s Comments
The reaction mixtures were monitored by TLC (hexane:ethyl acetate = 4:1).
Analytical Data（2-Phenylcyclohexanone (1)）
1H NMR (400 MHz, CDCl3); δ 7.37-7.31 (m, 2H), 7.30-7.22 (m, 1H), 7.17-7.12 (m, 2H), 3.62 (dd, 1H, J = 12.4, 6.9 Hz), 2.58-2.41 (m, 2H), 2.33-2.23 (m, 1H), 2.22-2.10 (m, 1H), 2.10-1.94 (m, 2H), 1.91-1.75 (m, 2H).
13C NMR (101 MHz, CDCl3); δ 210.5, 138.9, 128.6, 128.5, 127.0, 57.5, 42.3, 35.2, 27.9, 25.5.
Lead Reference
- Acceleration of the Dess-Martin Oxidation by Water
Application
Dess-Martin Periodinane Reagent
References
- M. Horikawa, K. Hashimoto, H. Shirahama, Tetrahedron Lett. 1993, 34, 331.
- J. N. Haseltine, M. P. Cabal, N. B. Mantlo, N. Iwasawa, D. S. Yamashita, R. S. Coleman, S. J. Danishefsky, G. K. Schulte, J. Am. Chem. Soc. 1991, 113, 3850.
- J. P. Burkhart, N. P. Peet, P. Bey, Tetrahedron Lett. 1988, 29, 3433.
- D. B. Dess, J. C. Martin, J. Org. Chem. 1983, 48, 4155.
- R. J. Linderman, D. M. Graves, Tetrahedron Lett. 1987, 28, 4259.
PubMed Literature
Articles/Brochures
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
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Specifications
C of A & Other Certificates
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Analytical Charts
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Other Documents
Related Products
Dess-Martin Periodinane (8-12% in Dichloromethane)
| Product # | D4477 |
| CAS RN | 87413-09-0 |
| Purity / Analysis Method: |