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CAS RN: 667-27-6 | Product Number: B1463
Ethyl Bromodifluoroacetate
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Purity: >98.0%(GC)
Synonyms:
- Bromodifluoroacetic Acid Ethyl Ester
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 5G |
$20.00
|
4 | 1 | ≥100 |
|
| 25G |
$53.00
|
3 | 7 | ≥80 |
|
| 250G |
$306.00
|
1 | 1 | ≥100 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
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*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | B1463 |
| Purity / Analysis Method | >98.0%(GC) |
| Molecular Formula / Molecular Weight | C__4H__5BrF__2O__2 = 202.98 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 667-27-6 |
| Reaxys Registry Number | 1906095 |
| PubChem Substance ID | 87564380 |
| SDBS (AIST Spectral DB) | 18950 |
| MDL Number | MFCD00042069 |
Specifications
| Appearance | Colorless to Light yellow to Light orange clear liquid |
| Purity(GC) | min. 98.0 % |
Properties (reference)
| Boiling Point | 113 °C |
| Flash point | 21 °C |
| Specific Gravity (20/20) | 1.57 |
| Refractive Index | 1.39 |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H314 : Causes severe skin burns and eye damage. H225 : Highly flammable liquid and vapor. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P240 : Ground/bond container and receiving equipment. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 : Keep container tightly closed. P243 : Take precautionary measures against static discharge. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 : Use only non-sparking tools. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 : Wash contaminated clothing before reuse. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P403 + P235 : Store in a well-ventilated place. Keep cool. P405 : Store locked up. |
Related Laws:
Transport Information:
| UN Number (DOT-AIR) | UN2924 |
| Class (DOT-AIR) | 3/8 |
| Packing Group (TCI-A) | II |
| HS Number | 2915.90.5050 |
Application
α,α-Difluoro Reformatsky Reagent
References
- A. Furstner, Synthesis 1989, 571.
- R. J. Linderman, D. M. Graves, J. Org. Chem. 1989, 54, 661.
- idem., Tetrahedron Lett. 1987, 28, 4259.
- T. Taguchi, O. Kitagawa, Y. Suda, S. Ohkawa, A. Hashimoto, Y. Iitaka, Y. Kobayashi, Tetrahedron Lett. 1988, 29, 5291.
- L. W. Hertel, J. S. Kroin, J. W. Misner, J. M. Tustin, J. Org. Chem. 1988, 53, 2406.
- D. Schirlin, S. Baltzer, J. M. Altenburger, Tetreahedron Lett. 1988, 29, 3687.
PubMed Literature
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
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Specifications
C of A & Other Certificates
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Analytical Charts
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