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CAS RN: 5000-65-7 | Product Number: A5505
3'-Methoxyphenacyl Bromide [for HPLC Labeling]
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![3'-Methoxyphenacyl Bromide [for HPLC Labeling]](/_ui/responsive/theme-tci/images/missing_product_zoom.jpg "3'-Methoxyphenacyl Bromide [for HPLC Labeling]")
Purity: >99.0%(GC)(T)
Synonyms:
- 3-(Bromoacetyl)anisole
- α-Bromo-3'-methoxyacetophenone
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 5G |
$109.00
|
1 | 1 | ≥40 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
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*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | A5505 |
| Purity / Analysis Method | >99.0%(GC)(T) |
| Molecular Formula / Molecular Weight | C__9H__9BrO__2 = 229.07 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive,Hygroscopic,Heat Sensitive |
| CAS RN | 5000-65-7 |
| Reaxys Registry Number | 510128 |
| PubChem Substance ID | 87563155 |
| SDBS (AIST Spectral DB) | 12601 |
| MDL Number | MFCD00000199 |
Specifications
| Appearance | White to Almost white powder to crystal |
| Purity(GC) | min. 99.0 % |
| Purity(Argentometric Titration) | min. 99.0 % |
| Melting point | 62.0 to 64.0 °C |
| Solubility in Methanol | almost transparency |
| Effect test of HPLC derivatization | Effective as labeling agent for Linoleic Acid , Stearic Acid |
| NMR | confirm to structure |
Properties (reference)
| Melting Point | 63 °C |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H314 : Causes severe skin burns and eye damage. H335 : May cause respiratory irritation. H290 : May be corrosive to metals. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P260 : Do not breathe dusts or mists. P234 : Keep only in original container. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P390 : Absorb spillage to prevent material damage. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 : Wash contaminated clothing before reuse. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. P406 : Store in corrosive resistant container with a resistant inner liner. P405 : Store locked up. |
Related Laws:
Transport Information:
| UN Number (DOT-AIR) | UN3261 |
| Class (DOT-AIR) | 8 |
| Packing Group (TCI-A) | II |
| HS Number | 2914.50.3000 |
Application
HPLC Labeling Reagent for Carboxylic Acids
The compound 1 is an HPLC labeling reagent, which has a bromoacetyl group and easily reacts with a carboxyl group to form the corresponding ester in the presence of a base. The resultant ester is stable and can reach the detector without any decomposition under reversed phase HPLC. An excellent chromatogram can be obtained by measuring at 254 nm, an absorption wavelength that is generally used for UV detection.
Application examples:
[Fatty acids] 1~ 3)
Dissolve 4 mg of a sample in 1 mL of N,N-dimethylformamide (DMF), and add the labeling reagent 1 (10 mg) in DMF (1 mL) and N,N-diisopropylethylamine (10 mg) in DMF (2 mL). Close the cap of the reaction vessel and incubate the solution at 60 °C for 1 h. Cool the resultant solution to room temperature and use it as an HPLC sample.
[Fatty acids] 1~ 3)
Dissolve 4 mg of a sample in 1 mL of N,N-dimethylformamide (DMF), and add the labeling reagent 1 (10 mg) in DMF (1 mL) and N,N-diisopropylethylamine (10 mg) in DMF (2 mL). Close the cap of the reaction vessel and incubate the solution at 60 °C for 1 h. Cool the resultant solution to room temperature and use it as an HPLC sample.
TCI Products Pamphlet
HPLC Labeling Reagents ( PDF 10MB )
HPLC Labeling Reagents ( PDF 10MB )
References
- 1)R. A. Miller, N. E. Bussell, C. Ricketts, J. Liquid Chromatogr. 1978, 1, 291.
- 2)N. E. Bussell, R. A. Miller, J. Liquid Chromatogr. 1979, 2, 697.
- 3)N. E. Bussell, A. Gross, R. A. Miller, J. Liquid Chromatogr. 1979, 2, 1337.
PubMed Literature
Articles/Brochures
TCIMAIL
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
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Specifications
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Other Documents
Related Products
3'-Methoxyphenacyl Bromide
| Product # | M0815 |
| CAS RN | 5000-65-7 |
| Purity / Analysis Method: | >98.0%(GC)(T) |