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CAS RN: 76855-69-1 | Product Number: A1124
(3R,4R)-4-Acetoxy-3-[(R)-(tert-butyldimethylsilyloxy)ethyl]-2-azetidinone
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![(3R,4R)-4-Acetoxy-3-[(R)-(tert-butyldimethylsilyloxy)ethyl]-2-azetidinone](/_ui/responsive/theme-tci/images/missing_product_zoom.jpg "(3R,4R)-4-Acetoxy-3-[(R)-(tert-butyldimethylsilyloxy)ethyl]-2-azetidinone")
Purity: >98.0%(N)
Synonyms:
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 5G |
$258.00
|
3 | 1 | 10 |
|
| 25G |
$931.00
|
1 | Contact Us | 1 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
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| Product Number | A1124 |
| Purity / Analysis Method | >98.0%(N) |
| Molecular Formula / Molecular Weight | C__1__3H__2__5NO__4Si = 287.43 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive |
| CAS RN | 76855-69-1 |
| Reaxys Registry Number | 4690202 |
| PubChem Substance ID | 87562608 |
| MDL Number | MFCD00077636 |
Specifications
| Appearance | White to Almost white powder to crystal |
| Purity(with Total Nitrogen) | min. 98.0 % |
| Melting point | 107.0 to 110.0 °C |
| Specific rotation [a]20/D | +53.0 to +59.0 deg(C=0.5, Toluene) |
| Solubility in Methanol | almost transparency |
| NMR | confirm to structure |
Properties (reference)
| Melting Point | 108 °C |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H319 : Causes serious eye irritation. H317 : May cause an allergic skin reaction. H411 : Toxic to aquatic life with long lasting effects. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P261 : Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. P273 : Avoid release to the environment. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P272 : Contaminated work clothing must not be allowed out of the workplace. P391 : Collect spillage. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302 + P352 : IF ON SKIN: Wash with plenty of soap and water. P333 + P313 : If skin irritation or rash occurs: Get medical advice/ attention. P363 : Wash contaminated clothing before reuse. |
Related Laws:
Transport Information:
| UN Number (DOT-AIR) | UN3077 |
| Class (DOT-AIR) | 9 |
| Packing Group (TCI-A) | III |
| HS Number | 2933.79.8500 |
Application
Riluzole: A Neuroprotective Agent
References
- Y. Nagao, T. Kumagai, S. Tamai, T. Abe, Y. Kuramoto, T. Taga, S. Aoyagi, Y. Nagase, M. Ochiai, Y. Inoue, E. Fujita, J. Am. Chem. Soc. 1986, 108, 4673.
- L. M. Fuentes, I. Shinkai, T. N. Salzmann, ibid. 1986, 108, 4675.
- F. Shirai, T. Nakai, J. Org. Chem. 1987, 52, 5491.
- T. Shibata, K. Iino, T. Tanaka, T. Hashimoto, Y. Kameyama, Y. Sugimura, Tetrahedron Lett. 1985, 26, 4739.
- M. Sugimura, T. Hiraoka, YAKUGAKU ZASSHI 1987, 107, 175.
PubMed Literature
Articles/Brochures
TCIMAIL
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Safety Data Sheet (SDS)
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Specifications
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