Make sure to sign up for an account today for exclusive coupons and free shipping on orders over $75!
Maximum quantity allowed is 999
Please select the quantity
CAS RN: 811-68-7 | Product Number: S0977
Silver(I) Trifluoromethanethiolate
×
![]()
×
Purity: >95.0%(T)
Synonyms:
- Trifluoromethanethiol Silver(I) Salt
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 1G |
$148.00
|
1 | 1 | ≥60 |
|
| 5G |
$534.00
|
5 | 1 | ≥60 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
* To send your quote request for bulk quantities, please click on the "Request Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | S0977 |
| Purity / Analysis Method | >95.0%(T) |
| Molecular Formula / Molecular Weight | CAgF__3S = 208.93 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Light Sensitive,Air Sensitive |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 811-68-7 |
| Reaxys Registry Number | 4151922 |
| PubChem Substance ID | 354333285 |
| MDL Number | MFCD25563234 |
Specifications
| Appearance | White to Light yellow to Light red powder to crystal |
| Purity(Precipitation Titration) | min. 95.0 % |
Properties (reference)
| Solubility in water | Insoluble |
| Solubility (slightly sol. in) | Methanol |
GHS
Related Laws:
Transport Information:
| HS Number | 2843.29.0100 |
Application
Trifluoromethylthiolating Agent Usable for Direct Dehydroxytrifluoromethylthiolation of Alcohols
Experimental procedure3): AgSCF3 (251 mg, 1.2 mmol, 3.0 eq.) and TBAI (1330 mg, 3.6 mmol, 9.0 eq.) are combined in a Schlenk tube. The tube is mounted with a reflux condenser and backfilled with N2, then toluene (4.0 mL) and alcohol (0.4 mmol, 1.0 eq.) are added. The tube is placed into a preheated oil bath at 80 °C with vigorous stirring. After 10 h, the reaction mixture is cooled to room temperature and filtered through a plug of silica (eluted with EtOAc). The filtrate is concentrated, and the product is purified by column chromatography on silica gel to give the desired product.
References
- 1)Pd-Catalyzed Synthesis of Ar-SCF3 Compounds under Mild Conditions
- 2)Silver-Mediated Radical Aryltrifluoromethylthiolation of Activated Alkenes
- 3)Direct Dehydroxytrifluoromethylthiolation of Alcohols Using Silver(I) Trifluoromethanethiolate and Tetra-n-butylammonium Iodide
- 4)Preparation of Trifluoromethyl Aryl Sulfides Using Silver(I)Trifluoromethanethiolate and an Inorganic Iodide
PubMed Literature
Articles/Brochures
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.
The requested SDS is not available.
Please Contact Us for more information.
Specifications
C of A & Other Certificates
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
Sample C of A
This is a sample C of A and may not represent a recently manufactured lot of the product.
A sample C of A for this product is not available at this time.
Analytical Charts
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
The requested analytical chart is not available. Sorry for the inconvenience.