Maintenance Notice (4:30 AM - 11:00 AM December 21, 2024): This website is scheduled to be unavailable due to maintenance. We appreciate your patience and understanding.
Published TCIMAIL newest issue No.197
Maximum quantity allowed is 999
Please select the quantity
Oxidizing Reagent
No.140(March 2010)
1 is a convenient, stable, and recyclable oxidizing agent, particularly useful in oxidizing allylic alcohols, as in the synthesis of geranial 3 from geraniol 2,1) and the oxidation of hemiacetal 5, such as an aldose sugar, into aldonolactone 6.2) Byproduct 4 can be oxidized using sodium hypochlorite and recycled back into 1 for reuse. It can also be used to transform bifunctional alcohol 7 into ester 8 by oxidative dimerization3) and in the synthesis of allylic alkoxyamines.4)
References
- 1)A stable and convenient reagent for the oxidation of alcohols
- 2)Oxidation of O-1 unprotected monosaccharides to lactones
- 3)Oxidative dimerization of polyfunctional primary alcohols to esters
- 4)Ene-like addition of an oxoammonium cation to alkenes
Related Compounds
- M0981
- N-Methylmorpholine N-Oxide (50% in Water, ca. 4.8 mol/L)
- T1560
- 2,2,6,6-Tetramethylpiperidine 1-Oxyl Free Radical
- A1348
- 4-Acetamido-2,2,6,6-tetramethylpiperidine 1-Oxyl Free Radical
- H0878
- 4-Hydroxy-2,2,6,6-tetramethylpiperidine 1-Oxyl Benzoate Free Radical
- M1197
- 4-Methoxy-2,2,6,6-tetramethylpiperidine 1-Oxyl Free Radical
- T1362
- Trimethylamine N-Oxide Anhydrous
- T0466
- Trimethylamine N-Oxide Dihydrate
The prices are subject to change without notice. Please confirm the newest price by our online catalog before placing an order.
In addition, sales products changes with areas. Please understand that a product is not available when the product details page is not displayed.
In addition, sales products changes with areas. Please understand that a product is not available when the product details page is not displayed.