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CAS RN: 131219-55-1 | Product Number: T1551
Tetrakis[N-phthaloyl-(S)-phenylalaninato]dirhodium Ethyl Acetate Adduct
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Purity: >90.0%(qNMR)
Synonyms:
- Dirhodium Tetrakis[N-phthaloyl-(S)-phenylalaninate] Ethyl Acetate Adduct
- Rh2(S-PTPA)4 EtOAc
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 100MG |
€290.00
|
2 | 33 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | T1551 |
| Purity / Analysis Method | >90.0%(qNMR) |
| Molecular Formula / Molecular Weight | C__6__8H__4__8N__4O__1__6Rh__2·C__4H__8O__2 = 1,471.06 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 131219-55-1 |
| PubChem Substance ID | 87577310 |
| MDL Number | MFCD00191695 |
Specifications
| Appearance | Green to Dark green powder to crystal |
| Purity(qNMR) | min. 90.0 % |
| NMR | confirm to structure |
Properties (reference)
GHS
Related Laws:
Transport Information:
| HS Number | 2843909000 |
Application
A Useful Chiral Dirhodium(II) Complex Catalyst
Experimental procedure2): the bis(ethyl acetate) adduct of Rh2(S-PTPA)4 (32 mg, 0.021 mmol) is added in one portion to a stirred solution of the 1 (300 mg, 1.04 mmol) in dry dichloromethane (3 mL) at 22 °C under argon atmosphere. After 6 h of stirring at this temperature, the resultant greenish solution is concentrated in vacuo and purified by silica gel column chromatography (hexane:ethyl acetate = 3:1) to give 2 (yield 97%, 60% ee).
References
- 1)Enantioselective Intramolecular C-H Insertion Reactions of α-Diazo β-Keto Esters Catalyzed by Dirhodium(II) Tetrakis[N-phthaloyl-(S)-phenylalaninate]: The Effect of the Substituent at the Insertion Site on Enantioselectivity
- 2)Enantioselective Intramolecular C-H Insertion Reactions of N-Alkyl-N-tert-Butyl-α-Methoxycarbonyl-α-Diazoacetamides Catalyzed by Dirhodium(II) Carboxylates: Catalytic, Asymmetric Construction of 2-Azetidinones
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