Published TCIMAIL newest issue No.197
Maximum quantity allowed is 999
Please select the quantity
CAS RN: 7722-84-1 | Product Number: H1222
Hydrogen Peroxide (35% in Water)
×
![]()
×
Purity:
Synonyms:
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 300ML |
€26.00
|
30 | ≥100 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | H1222 |
| Molecular Formula / Molecular Weight | H__2O__2 = 34.01 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Condition to Avoid | Light Sensitive |
| CAS RN | 7722-84-1 |
| Reaxys Registry Number | 3587191 |
| Merck Index (14) | 4798 |
| MDL Number | MFCD00011333 |
Specifications
| Appearance | Colorless to Almost colorless clear liquid |
| Concentration(Redox method) | 35.0 to 36.0 w/w% |
Properties (reference)
| Melting Point | -26 °C |
| Boiling Point | 107 °C |
| Refractive Index | 1.34 |
| Solubility in water | Completely miscible |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H302 + H332 : Harmful if swallowed or if inhaled. H314 : Causes severe skin burns and eye damage. H370 : Causes damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H351 : Suspected of causing cancer. H335 : May cause respiratory irritation. H271 : May cause fire or explosion; strong oxidizer. |
| Precautionary Statements | P260 : Do not breathe mist or vapours. P220 : Keep away from clothing and other combustible materials. P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P371 + P380 + P375 : In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. |
Related Laws:
| EC Number | 231-765-0 |
| RTECS# | MX0899500 |
Transport Information:
| UN Number | UN2014 |
| Class | 5.1 / 8 |
| Packing Group | II |
| HS Number | 2847000000 |
Application
TCI Practical Example: Oxidation of Aniline Moiety Using Hydrogen Peroxide
-
Used Chemicals
-
Procedure
-
To a solution of p-anisidine (123 mg, 1.0 mmol) and potassium carbonate (138 mg, 1.0 mmol) in acetonitrile (5 mL) was added hydrogen peroxide aq. (35%, 0.5 mL) at r.t. and the mixture was stirred at r.t. for 1 h. Potassium carbonate (138 mg, 1.0 mmol) and hydrogen peroxide aq. (0.5 mL) were further added at r.t. and the mixture was stirred at r.t. for overnight. The reaction mixture was diluted with dichloromethane (25 mL) and washed with saturated sodium thiosulfate aq. (50 mL), saturated aqueous sodium bicarbonate solution (50 mL), dried over sodium sulfate and filtered. The solvent was removed under reduced pressure and the residue was purified by column chromatography (on silica gel, dichloromethane:hexane = 0:1 - 1:4), giving 4-nitroanisole as a pale yellow solid (108 mg, 70% yield).
-
Experimenter’s Comments
-
The reaction mixture was monitored by UPLC.
-
Analytical Data
-
4-Nitroanisole
1H NMR (270 MHz, CDCl3); δ 8.21 (d, 2H, J = 9.2 Hz), 6.96 (d, 2H, J = 9.2 Hz), 3.91 (s, 3H).
-
Lead Reference
-
- Base promoted peroxide systems for the efficient synthesis of nitroarenes and benzamides
PubMed Literature
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.
The requested SDS is not available.
Please Contact Us for more information.
Specifications
C of A & Other Certificates
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
Sample C of A
This is a sample C of A and may not represent a recently manufactured lot of the product.
A sample C of A for this product is not available at this time.
Analytical Charts
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
The requested analytical chart is not available. Sorry for the inconvenience.