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Published TCIMAIL newest issue No.197
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CAS RN: 26042-63-7 | Product Number: S0981
Silver Hexafluorophosphate
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Purity: >98.0%(T)
Synonyms:
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 1G |
€30.00
|
Contact Us | ≥100 |
|
| 5G |
€118.00
|
Contact Us | 16 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | S0981 |
| Purity / Analysis Method | >98.0%(T) |
| Molecular Formula / Molecular Weight | AgPF__6 = 252.83 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Light Sensitive,Hygroscopic |
| CAS RN | 26042-63-7 |
| Reaxys Registry Number | 13607729 |
| PubChem Substance ID | 354333698 |
| MDL Number | MFCD00003415 |
Specifications
| Appearance | White to Light yellow to Light red powder to crystal |
| Purity(Precipitation Titration) | min. 98.0 % |
Properties (reference)
| Melting Point | 102 °C(dec.) |
| Maximum Absorption Wavelength | 413(CHCl3) nm |
| Solubility in water | Soluble |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H314 : Causes severe skin burns and eye damage. H290 : May be corrosive to metals. |
| Precautionary Statements | P260 : Do not breathe dust. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. |
Related Laws:
| EC Number | 247-428-6 |
Transport Information:
| UN Number | UN3260 |
| Class | 8 |
| Packing Group | II |
| HS Number | 2843290000 |
Application
A C-Arylation of N-Tosyl Aziridines
Experimental procedure: A mixture of 1 (1 mmol, 273 mg), anisole (2 mmol, 100 µL) and AgPF6 (0.02 mmol, 5 mg) in 3 mL of dry dichloroethane are stirred at 30 - 35 °C. Then the reaction mixture is diluted with water (5 mL) and extracted with dichloroethane (5 mL). The combined organic layers are dried over anhydrous sodium sulfate, concentrated in vacuo and the resulting product is purified by column chromatography on silica gel (ethyl acetate : petroleum ether = 1 : 10) to afford 2 (305 mg, 80% yield).
References
- A facile C-arylation of N-tosyl aziridines via Ag(I) catalysis
PubMed Literature
Product Documents (Note: Some products will not have analytical charts available.)
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