Published TCIMAIL newest issue No.196
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CAS RN: 130004-33-0 | Product Number: R0147
[RuCl(p-cymene)((S)-binap)]Cl
Purity: >90.0%(HPLC)
Synonyms:
- Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) Chloride
Product Documents:
Size | Unit Price | Belgium | Japan* | Quantity |
---|---|---|---|---|
200MG |
€34.00
|
1 | 10 |
|
1G |
€116.00
|
3 | 14 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
Supplemental Product Information:
This product was merchandised under the technical tie-up with TAKASAGO INTERNATIONAL CORPORATION.
We offer this product only in quantities for laboratory use.
Product Number | R0147 |
Purity / Analysis Method | >90.0%(HPLC) |
Molecular Formula / Molecular Weight | C__5__4H__4__6Cl__2P__2Ru = 928.88 |
Physical State (20 deg.C) | Solid |
Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
Store Under Inert Gas | Store under inert gas |
Condition to Avoid | Air Sensitive |
CAS RN | 130004-33-0 |
Reaxys Registry Number | 16702130 |
PubChem Substance ID | 253662112 |
MDL Number | MFCD00134456 |
Specifications
Appearance | White to Brown to Dark purple powder to crystal |
Purity(HPLC) | min. 90 area% |
Properties (reference)
Solubility in water | Insoluble |
GHS
Related Laws:
Transport Information:
HS Number | 2843909000 |
Application
An efficient ruthenium catalyst usable for high enatioselective hydrogenation of ketones
References
- Homogeneous asymmetric hydrogenation of o-chloroacetophenone to enantiomerically pure o -chloro-(1-phenyl)ethanol catalyzed by BINAP-Ru(II) complex
- Cationic BINAP-Ru(II) Halide Complexes: Highly Efficient Catalysts for Stereoselective Asymmetric Hydrogenation of .alpha.- and .beta.-Functionalized Ketones
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