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CAS RN: 2226-96-2 | Product Number: H0865
4-Hydroxy-2,2,6,6-tetramethylpiperidine 1-Oxyl Free Radical
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Purity: >98.0%(GC)
Synonyms:
- 4-Hydroxy-TEMPO Free Radical
- TEMPOL Free Radical
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 5G |
€61.00
|
Contact Us | ≥100 |
|
| 25G |
€205.00
|
2 | ≥100 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | H0865 |
| Purity / Analysis Method | >98.0%(GC) |
| Molecular Formula / Molecular Weight | C__9H__1__8NO__2 = 172.25 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Light Sensitive,Hygroscopic |
| CAS RN | 2226-96-2 |
| Reaxys Registry Number | 11328213 |
| PubChem Substance ID | 87571222 |
| Merck Index (14) | 9141 |
| MDL Number | MFCD00006478 |
Specifications
| Appearance | Light yellow to Brown powder to lump |
| Purity(GC) | min. 98.0 % |
| Purity(Iodometric Titration) | min. 97.0 % |
| Melting point | 69.0 to 75.0 °C |
| Solubility in Methanol | very faint turbidity |
Properties (reference)
| Melting Point | 72 °C |
| Solubility in water | Soluble |
| Solubility (soluble in) | Methanol |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H302 : Harmful if swallowed. H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P270 : Do not eat, drink or smoke when using this product. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. |
Related Laws:
| EC Number | 218-760-9 |
| RTECS# | TN8991000 |
Transport Information:
| HS Number | 2933399990 |
Application
Aerobic Oxidation of Alcohols Using 4-Hydroxy-TEMPO Adsorbed on Silica Gel
Typical Procedure:
Preparation of [4-hydroxy-TEMPO + NaCl]/SiO2
Silica gel (9.77 g) is added to the solution of 4-hydroxy-TEMPO (0.17 g) and NaCl (0.06 g) in water (50 mL), and the mixture is stirred at room temperature for half an hour. The water is removed by rotary evaporator under reduced pressure (65 °C and 40 mbar).
Aerobic Oxidation of Alcohols
A mixture of alcohols (2.0 mmol), Fe(NO3)3?9H2O (5?8 mol%) and [4-hydroxy-TEMPO + NaCl]/SiO2 [(0.1 + 0.1) mmol/g, 1.0 g] is stirred in DCE (5 mL) under air (1 atm) at room temperature, and then the used supported reagents are removed by filtration. Product yield is determined by GLC analysis using n-dodecane as an internal standard.
Preparation of [4-hydroxy-TEMPO + NaCl]/SiO2
Silica gel (9.77 g) is added to the solution of 4-hydroxy-TEMPO (0.17 g) and NaCl (0.06 g) in water (50 mL), and the mixture is stirred at room temperature for half an hour. The water is removed by rotary evaporator under reduced pressure (65 °C and 40 mbar).
Aerobic Oxidation of Alcohols
A mixture of alcohols (2.0 mmol), Fe(NO3)3?9H2O (5?8 mol%) and [4-hydroxy-TEMPO + NaCl]/SiO2 [(0.1 + 0.1) mmol/g, 1.0 g] is stirred in DCE (5 mL) under air (1 atm) at room temperature, and then the used supported reagents are removed by filtration. Product yield is determined by GLC analysis using n-dodecane as an internal standard.
Reference
PubMed Literature
Articles/Brochures
TCIMAIL
[Research Articles] Aerobic Oxidation of Alcohols Using 4-Hydroxy-TEMPO Adsorbed on Silica GelProduct Documents (Note: Some products will not have analytical charts available.)
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