Published TCIMAIL newest issue No.196
Maximum quantity allowed is 999
Please select the quantity
CAS RN: 2950-43-8 | Product Number: H0530
Hydroxylamine-O-sulfonic Acid
×
![]()
×
Purity: >90.0%(T)
Synonyms:
- HSA
- HOSA
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 25G |
48,00 €
|
6 | 7 |
|
| 100G |
137,00 €
|
1 | 1 |
|
| 500G |
439,00 €
|
1 | Contact Us |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | H0530 |
| Purity / Analysis Method | >90.0%(T) |
| Molecular Formula / Molecular Weight | H__3NO__4S = 113.09 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Hygroscopic |
| CAS RN | 2950-43-8 |
| Reaxys Registry Number | 878303 |
| PubChem Substance ID | 87570919 |
| MDL Number | MFCD00011604 |
Specifications
| Appearance | White to Almost white powder to crystal |
| Purity(Iodometric Titration) | min. 90.0 % |
Properties (reference)
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H302 + H312 + H332 : Harmful if swallowed, in contact with skin or if inhaled. H314 : Causes severe skin burns and eye damage. H290 : May be corrosive to metals. |
| Precautionary Statements | P260 : Do not breathe dust. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. |
Related Laws:
| EC Number | 220-971-6 |
| RTECS# | NC5427000 |
Transport Information:
| UN Number | UN3261 |
| Class | 8 |
| Packing Group | III |
| HS Number | 2825100090 |
Application
Hydroxylamine for the Transition-Metal-Free Amination Reaction
Experimental procedure:
To the boronic acid (1.0 mmol) in MeCN (5 mL) is added HSA (170 mg, 1.5 eq.), followed by aq. NaOH solution (1 mol/L, 5 mL). The biphasic mixture is stirred for 16 h at room temperature. The reaction mixture is diluted with H2O (30 mL, saturated aq. NH4Cl for products containing acidic functional groups) and extracted with EtOAc (2 × 30 mL). The combined organic extracts are dried (Na2SO4) and concentrated in vacuo. The residue is purified by flash chromatography (EtOAc:hexanes) to afford the amine product.
References
- Transition-Metal-Free Access to Primary Anilines from Boronic Acids and a Common +NH2 Equivalent.
Application
Synthesis of N-H Aziridines from Unactivated Olefins Using Hydroxylamine-O-Sulfonic Acid
References
- Direct and Stereospecific Synthesis of N-H and N-Alkyl Aziridines from Unactivated Olefins Using Hydroxylamine-O-Sulfonic Acids
PubMed Literature
Articles/Brochures
TCIMAIL
[Product Highlights] Hydroxylamine for the Transition-Metal-Free Amination Reaction[Product Highlights] Synthesis of N-H Aziridines from Unactivated Olefins Using Hydroxylamine-O-Sulfonic Acid
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.
The requested SDS is not available.
Please Contact Us for more information.
Specifications
C of A & Other Certificates
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
Sample C of A
This is a sample C of A and may not represent a recently manufactured lot of the product.
A sample C of A for this product is not available at this time.
Analytical Charts
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
The requested analytical chart is not available. Sorry for the inconvenience.