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CAS RN: 543-75-9 | Product Number: D2287
1,4-Dioxene
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Purity: >98.0%(GC)
Synonyms:
- 2,3-Dihydro-1,4-dioxine
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 1G |
143,00 €
|
2 | 12 |
|
| 5G |
458,00 €
|
4 | 3 |
|
| 25G |
1 600,00 €
|
6 | Contact Us |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | D2287 |
| Purity / Analysis Method | >98.0%(GC) |
| Molecular Formula / Molecular Weight | C__4H__6O__2 = 86.09 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive |
| CAS RN | 543-75-9 |
| Reaxys Registry Number | 1310 |
| PubChem Substance ID | 87568724 |
| SDBS (AIST Spectral DB) | 35998 |
| MDL Number | MFCD00082537 |
Specifications
| Appearance | Colorless to Light yellow to Light orange clear liquid |
| Purity(GC) | min. 98.0 % |
Properties (reference)
| Boiling Point | 94 °C |
| Flash point | 1 °C |
| Specific Gravity (20/20) | 1.08 |
| Refractive Index | 1.44 |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H225 : Highly flammable liquid and vapour. |
| Precautionary Statements | P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 : Keep container tightly closed. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. |
Related Laws:
Transport Information:
| UN Number | UN1993 |
| Class | 3 |
| Packing Group | II |
| HS Number | 2932990090 |
Application
Useful Synthon
References
- Review : The chemistry of 1,4-Dioxene
- Synthesis of α-keto thioketals
- Synthesis of α,α'-dihydroxy ketones
- Synthesis of α-hydroxymethyl ketones
- Synthesis of α-keto acids
- Photocycloaddition reaction
- a) G. Kaupp, M. Stark, H. Fritz, Chem. Ber. 1978, 111, 3624.
- b) R. Huisgen, L. A. Feiler, P. Otto, ibid. 1969, 102, 3405.
- idem., ibid. 1969, 102, 3444.
- c) N. R. Lazear, J. H. Schauble, J. Org. Chem. 1974, 39, 2069.
- . C. Freilich, K. S. Peters, J. Am. Chem. Soc. 1985, 107, 3819.
- d) J.-M. Bernassau, A. Bouillot, M. Fétizon, I. Hanna, E. R. Maia, J. Org. Chem. 1987, 52, 1993.
- . H. M. Hill, S. T. Reid, J. Chem. Soc., Chem. Commun. 1983, 501.
- . Wenkert, R. S. Greenberg, M. S. Raju, J. Org. Chem. 1985, 50, 4681.
- a) G. Kaupp, M. Stark, H. Fritz, Chem. Ber. 1978, 111, 3624.
PubMed Literature
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